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Synthesis of a novel amphoteric copolymer and its application as a dispersant for coal water slurry preparation.

ABSTRACT: In this work, a novel amphoteric copolymer named Poly(sodium p-styrenesulfonate-co-acrylic acid-co-diallyldimethylammonium chloride) (P(SS-co-AA-co-DMDAAC)) was synthesized via free radical polymerization. Afterwards, P(SS-co-AA-co-DMDAAC) was explored for use as a dispersant in coal water slurry (CWS) preparation. The structure of P(SS-co-AA-co-DMDAAC) was verified by Fourier transform infrared spectroscopy and nuclear magnetic resonance. The synthetic conditions were optimized as the feed ratio of AA to SS was 1 : 1 (for Yulin coal) or 1.5 : 1 (for Yili coal), and DMDAAC dosage was 4.0 wt% (for Yulin coal) and 6.0 wt% (for Yili coal) toward total monomers. The performances of P(SS-co-AA-co-DMDAAC) as a dispersant for CWS were evaluated by various technologies, such as apparent viscosity, zeta potential, static stability and contact angle measurements. The results revealed that the optimized dosage of P(SS-co-AA-co-DMDAAC) in CWS preparation was 0.3 and 0.4 wt% for Yulin coal and Yili coal respectively. In this optimum condition, CWS prepared using P(SS-co-AA-co-DMDAAC) as dispersant showed a typical shear thinning behaviour and excellent stability, which are desired in industries. The rheological models also confirmed the pseudo-plastic characteristics of CWS. Finally, compared with the widely used anionic dispersant naphthalene sulphonate formaldehyde condensate (NSF) and poly(sodium p-styrenesulfonate) (PSS), P(SS-co-AA-co-DMDAAC) developed in this work exhibited better slurry making performance. The introduction of cationic functional groups promoted the adsorption of the dispersant, which further enhanced the electrostatic repulsion and steric hindrance among coal particles. Accordingly, the viscosity of CWS decreased and static stability enhanced.

SUBMITTER: Du L

PROVIDER: S-EPMC7890484 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Synthesis of a novel amphoteric copolymer and its application as a dispersant for coal water slurry preparation.

Du Lun L Zhang Guanghua G Yang Dongdong D Luo Jie J Liu Yewei Y Zhang Wanbin W Zhang Ce C Li Junguo J Zhu Junfeng J

Royal Society open science 20210113 1

In this work, a novel amphoteric copolymer named Poly(sodium p-styrenesulfonate-co-acrylic acid-co-diallyldimethylammonium chloride) (P(SS-co-AA-co-DMDAAC)) was synthesized via free radical polymerization. Afterwards, P(SS-co-AA-co-DMDAAC) was explored for use as a dispersant in coal water slurry (CWS) preparation. The structure of P(SS-co-AA-co-DMDAAC) was verified by Fourier transform infrared spectroscopy and nuclear magnetic resonance. ...[more]

PMID: 33614083

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Project description:Despite its complex structure, coal has shown to be a promising precursor for graphene synthesis by chemical vapor deposition (CVD). However, the presence of heteroatoms and aliphatic chains in coal can lead to defects in the graphene lattice, preventing the formation of pristine graphene layers. Therefore, the goal of this study was to formulate a multistep coal fractionation scheme to extract and characterize the most aromatic fractions and explore their potential as graphene precursors. The scheme consisted of direct coal liquefaction under different conditions, Soxhlet extraction with heptane then toluene, and preparative liquid chromatography on silica gel using heptol solutions with different heptane/toluene ratios. The fractions obtained by this process were analyzed by proton nuclear magnetic resonance, thermogravimetric and elemental analyses, and automated SAR-AD (saturates, aromatics, resins-asphaltene determinator) separations. This characterization allowed the identification of two aromatic fractions with and without heteroatoms, which were subsequently used for graphene synthesis by CVD on nickel and copper foils. Raman spectrometry revealed that both fractions primarily formed defect-free multilayered graphene with approximately 11 layers on nickel due to the high solubility of carbon and the defect-healing effect of nickel. On the other hand, these fractions generated amorphous carbon on copper due to the high solubility of hydrogen in copper, which competed with carbon. Molecules in the more aromatic heteroatom-free fraction still contained alkyl pendant substituents and did not share the same planarity and symmetry to form defect-free graphene on copper. Thus, the quality of graphene was governed by the substrate on nickel and by the precursor quality on copper. When deposited directly on lacey carbon-coated copper grids of a transmission electron microscope, the heteroatom-free fraction gave rise to much larger graphene domains. The presence of heteroatoms promoted the formation of small self-assembled agglomerates of amorphous carbon.

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Synthesis of a novel amphoteric copolymer and its application as a dispersant for coal water slurry preparation.

Publications

Synthesis of a novel amphoteric copolymer and its application as a dispersant for coal water slurry preparation.

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