Ontology highlight
ABSTRACT:
SUBMITTER: Wallach C
PROVIDER: S-EPMC7898805 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Wallach Christoph C Geitner Felix S FS Karttunen Antti J AJ Fässler Thomas F TF
Angewandte Chemie (International ed. in English) 20201201 5
The unique three-dimensional structure of spherical, homoatomic nine-atom germanium clusters opens various possibilities for the spatial arrangement of functional groups. Ligands comprising lone pairs have recently been introduced in the cluster sphere, and we now report the addition of a boranyl group to the cluster featuring a Ge-B exo-cluster bond. The reaction of the twofold-silylated cluster [Ge<sub>9</sub> {Si(TMS)<sub>3</sub> }<sub>2</sub> ]<sup>2-</sup> (TMS=trimethylsilyl) with 2-chloro ...[more]