Dataset Information

Carbonaceous Particulate Matter Emitted from a Pellet-Fired Biomass Boiler.

ABSTRACT: Biomass pellets are a source of renewable energy; although, the air pollution and exposure risks posed by the emissions from burning pellets in biomass boilers (BBs) are uncertain. The present study examines the organic species in fine particle matter (PM) emissions from an BB firing switchgrass (SwG) and hardwood (HW) biomass pellets using different test cycles. The organic and elemental carbon (OC and EC) content and select semivolatile organic compounds (SVOCs) in filter-collected PM were identified and quantified using thermal-optical analysis and gas chromatography-mass spectrometry (GC-MS), respectively. Fine PM emissions from the BB ranged from 0.4 g/kg to 2.91 g/kg of pellets burned of which 40% ± 17% w/w was carbon. The sum of GC-MS quantified SVOCs in the PM emissions varied from 0.13 to 0.41 g/g OC. Relatively high levels of oxygenated compounds were observed in the PM emissions, and the most predominant individual SVOC constituent was levoglucosan (12.5-320 mg/g OC). The effect of boiler test cycle on emissions was generally greater than the effect due to pellet fuel type. Organic matter emissions increased at lower loads, owing to less than optimal combustion performance. Compared with other types of residential wood combustion studies, pellet burning in the current BB lowered PM emissions by nearly an order of magnitude. PM emitted from burning pellets in boilers tested across multiple studies also contains comparatively less carbon; however, the toxic polycyclic aromatic hydrocarbons (PAH) in the PM tested across these pellet-burning studies varied substantially, and produced 2-10 times more benzo[k]fluoranthene, dibenz[a,h]anthracene and indeno[1,2,3-c,d]pyrene on average. These results suggest that further toxicological evaluation of biomass pellet burning emissions is required to properly understand the risks posed.

SUBMITTER: Hays MD

PROVIDER: S-EPMC7900939 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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Carbonaceous Particulate Matter Emitted from a Pellet-Fired Biomass Boiler.

Hays Michael D MD Kinsey John J George Ingrid I Preston William W Singer Carl C Patel Bakul B

Atmosphere 20190901 9

Biomass pellets are a source of renewable energy; although, the air pollution and exposure risks posed by the emissions from burning pellets in biomass boilers (BBs) are uncertain. The present study examines the organic species in fine particle matter (PM) emissions from an BB firing switchgrass (SwG) and hardwood (HW) biomass pellets using different test cycles. The organic and elemental carbon (OC and EC) content and select semivolatile organic compounds (SVOCs) in filter-collected PM were ide ...[more]

PMID: 33628468

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Project description:Biomass pellets are emerging as a cleaner alternative to traditional biomass fuels. The potential benefits of using biomass pellets include improving energy utilization efficiency and reducing emissions of air pollutants. To assess the environmental, climate, and health significance of replacing traditional fuels with biomass pellets, it is critical to measure the emission factors (EFs) of various pollutants from pellet burning. However, only a few field measurements have been conducted on the emissions of carbon monoxide (CO), particulate matter (PM), and polycyclic aromatic hydrocarbons (PAHs) from the combustion of pellets. In this study, pine wood and corn straw pellets were burned in a pellet burner (2.6 kW), and the EFs of CO, organic carbon, elemental carbon, PM, and PAHs (EF(CO), EF(OC), EF(EC), EF(PM), and EF(PAH)) were determined. The average EF(CO), EF(OC), EF(EC), and EF(PM) were 1520 ± 1170, 8.68 ± 11.4, 11.2 ± 8.7, and 188 ± 87 mg/MJ for corn straw pellets and 266 ± 137, 5.74 ± 7.17, 2.02 ± 1.57, and 71.0 ± 54.0 mg/MJ for pine wood pellets, respectively. Total carbonaceous carbon constituted 8 to 14% of the PM mass emitted. The measured values of EF(PAH) for the two pellets were 1.02 ± 0.64 and 0.506 ± 0.360 mg/MJ, respectively. The secondary side air supply in the pellet burner did not change the EFs of most pollutants significantly (p > 0.05). The only exceptions were EF(OC) and EF(PM) for pine wood pellets because of reduced combustion temperatures with the increased air supply. In comparison with EFs for the raw pine wood and corn straw, EF(CO), EF(OC), EF(EC), and EF(PM) for pellets were significantly lower than those for raw fuels (p < 0.05). However, the differences in EF(PAH) were not significant (p > 0.05). Based on the measured EFs and thermal efficiencies, it was estimated that 95, 98, 98, 88, and 71% reductions in the total emissions of CO, OC, EC, PM, and PAHs could be achieved by replacing the raw biomass fuels combusted in traditional cooking stoves with pellets burned in modern pellet burners.

Project description:The adverse effects of atmospheric particulate matter (PM) on health and ecosystems, as well as on meteorology and climate change, are well known to the scientific community. It is therefore undeniable that a good understanding of the sources of PM is crucial for effective control of emissions and to protect public health. One of the major contributions to atmospheric PM is biomass burning, a practice used both in agriculture and home heating, which can be traced and identified by analyzing sugars emitted from the combustion of cellulose and hemicellulose that make up biomass. In this review comparing almost 200 selected articles, we highlight the most recent studies that broaden such category of tracers, covering research publications on residential wood combustions, open-fire or combustion chamber burnings and ambient PM in different regions of Asia, America and Europe. The purpose of the present work is to collect data in the literature that indicate a direct correspondence between biomass burning and saccharides emitted into the atmosphere with regard to distinguishing common sugars attributed to biomass burning from those that have co-causes of issue. In this paper, we provide a list of 24 compounds, including those most commonly recognized as biomass burning tracers (i.e., levoglucosan, mannosan and galactosan), from which it emerges that monosaccharide anhydrides, sugar alcohols and primary sugars have been widely reported as organic tracers for biomass combustion, although it has also been shown that emissions of these compounds depend not only on combustion characteristics and equipment but also on fuel type, combustion quality and weather conditions. Although it appears that it is currently not possible to define a single compound as a universal indicator of biomass combustion, this review provides a valuable tool for the collection of information in the literature and identifies analytes that can lead to the determination of patterns for the distribution between PM generated by biomass combustion.

Dataset Information

Carbonaceous Particulate Matter Emitted from a Pellet-Fired Biomass Boiler.

Publications

Carbonaceous Particulate Matter Emitted from a Pellet-Fired Biomass Boiler.

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