Ontology highlight
ABSTRACT:
SUBMITTER: Gravatt CS
PROVIDER: S-EPMC7902453 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Gravatt Christopher S CS Melecio-Zambrano Luis L Yoon Tehshik P TP
Angewandte Chemie (International ed. in English) 20201229 8
The sole method available for the photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reaction. The [Cu(OTf)]<sub>2</sub> ⋅benzene catalyst that has been standard in this reaction for many decades, however, is air-sensitive, prone to photodecomposition, and poorly reactive towards sterically bulky alkene substrates. Using bench-stable precursors, an improved catalyst system with superior reactivity and photostability has been designed, and it offers significant ...[more]