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Removal of Sulfadiazine by Polyamide Nanofiltration Membranes: Measurement, Modeling, and Mechanisms.

ABSTRACT: In this study, a complete steric, electrostatic, and dielectric mass transfer model is applied to investigate the separation mechanism of typical antibiotic sulfadiazine by NF90, NF270, VNF-8040 and TMN20H-400 nanofiltration membranes. FTIR and XPS analysis clearly indicate that the membranes we used possess skin layers containing both amine and carboxylic acid groups that can be distributed in an inhomogeneous fashion, leading to a bipolar fixed charge distribution. We compare the theoretical and experimental rejection rate of the sulfadiazine as a function of the pressure difference across the nanopore for the four polyamide membranes of inhomogeneously charged nanopores. It is shown that the rejection rate of sulfadiazine obtained by the solute transport model has similar qualitative results with that of experiments and follows the sequence: RNF90>RVNF2-8040>RNF270>RTMN20H-400. The physical explanation can be attributed to the influence of the inhomogeneous charge distribution on the electric field that arises spontaneously so as to maintain the electroneutrality within the nanopore.

SUBMITTER: Zhu H

PROVIDER: S-EPMC7912794 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Removal of Sulfadiazine by Polyamide Nanofiltration Membranes: Measurement, Modeling, and Mechanisms.

Zhu Haochen H Hu Bo B Yang Fengrui F

Membranes 20210202 2

In this study, a complete steric, electrostatic, and dielectric mass transfer model is applied to investigate the separation mechanism of typical antibiotic sulfadiazine by NF90, NF270, VNF-8040 and TMN20H-400 nanofiltration membranes. FTIR and XPS analysis clearly indicate that the membranes we used possess skin layers containing both amine and carboxylic acid groups that can be distributed in an inhomogeneous fashion, leading to a bipolar fixed charge distribution. We compare the theoretical a ...[more]

PMID: 33540550

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Project description:Given the huge significance of organic solvents in several industrial processes, the use of membranes for recovering the solvents has evolved into an industrially viable process. The current work has been focused on studying the effect of minor changes in the chemistry of the reacting monomers on the organic solvent nanofiltration/solvent resistance nanofiltration (OSN/SRNF) performance of the membranes. The two aliphatic amines with varying aliphatic chain lengths between primary and secondary amines were selected for this purpose. Based on the structure of the resultant active layer, the Janus nanofiltration performance of the membrane was evaluated. The two membranes, 4A-TPC@crosslinked PAN and 4A-3P@crosslinked PAN were fabricated by using two different tetra-amines, 4A (N,N'-bis(3-aminopropyl)ethylenediamine) and 4A-3P (N,N'-Bis(2-aminoethyl)-1,3-propanediamine) crosslinked with terephthaloyl chloride (TPC) on a crosslinked polyacryonitrile (PAN) support through interfacial polymerization (IP). The presence of multiple hydrophobic -CH2- groups in the structures of the aliphatic amines 4A and 4A-3P develops hydrophobic sites in the hydrophilic polyamide active layers of the membranes. In addition, 4A has two secondary amino groups separated by ethylene (-CH2-CH2-) groups, whereas in 4A-3P, the two secondary amino groups are separated by propylene (-CH2-CH2-CH2-) leading to variation in the structural features and performance of the two membranes. Both membranes were fully characterized by several membrane characterization techniques and applied for OSN/SRNF using both polar (methanol, ethanol, and isopropanol) and non-polar (n-hexane and toluene) solvents. Different dyes (Congo red, Eriochrome black T, and Methylene blue) were used as model solutes during the filtration experiment. The 4A-3P-TPC@crosslinked PAN showed n-hexane and toluene flux of 109.9 LMH and 95.5 LMH, respectively. The Congo red (CR) showed the highest rejection, reaching 99.1% for the 4A-TPC@Crosslinked PAN membrane and 98.8% for the 4A-3P-TPC@Crosslinked PAN membrane.

Dataset Information

Removal of Sulfadiazine by Polyamide Nanofiltration Membranes: Measurement, Modeling, and Mechanisms.

Publications

Removal of Sulfadiazine by Polyamide Nanofiltration Membranes: Measurement, Modeling, and Mechanisms.

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