Lead-Free Metal Halide Perovskites for Hydrogen Evolution from Aqueous Solutions.

ABSTRACT: Metal halide perovskites (MHPs) exploitation represents the next big frontier in photovoltaic technologies. However, the extraordinary optoelectronic properties of these materials also call for alternative utilizations, such as in solar-driven photocatalysis, to better address the big challenges ahead for eco-sustainable human activities. In this contest the recent reports on MHPs structures, especially those stable in aqueous solutions, suggest the exciting possibility for efficient solar-driven perovskite-based hydrogen (H₂) production. In this minireview such works are critically analyzed and classified according to their mechanism and working conditions. We focus on lead-free materials, because of the environmental issue represented by lead containing material, especially if exploited in aqueous medium, thus it is important to avoid its presence from the technology take-off. Particular emphasis is dedicated to the materials composition/structure impacting on this catalytic process. The rationalization of the distinctive traits characterizing MHPs-based H₂ production could assist the future expansion of the field, supporting the path towards a new class of light-driven catalysts working in aqueous environments.

SUBMITTER: Armenise V 

PROVIDER: S-EPMC7915764 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature