Ontology highlight
ABSTRACT:
SUBMITTER: Sidler D
PROVIDER: S-EPMC7928910 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
The journal of physical chemistry letters 20201229 1
A fundamental question in the field of polaritonic chemistry is whether collective coupling implies local modifications of chemical properties scaling with the ensemble size. Here we demonstrate from first-principles that an impurity present in a collectively coupled chemical ensemble features such locally scaling modifications. In particular, we find the formation of a novel dark state for a nitrogen dimer chain of variable size, whose local chemical properties are altered considerably at the i ...[more]