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A 3D Silverton-Type Polyoxomolybdate Based on {PrMo12O42}: Synthesis, Structure, Photoluminescence and Magnetic Properties.


ABSTRACT: A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH4{Mn4[PrMo12O42]}·18H2O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo12O42} has formed 3D frameworks via the {MnO6} linker. The excitation of compound 1 in solid state at 375 nm displays red emission. Moreover, variable temperature magnetic susceptibility measurements indicate that the magnetic behavior in compound 1 is dominated by antiferromagnetic interactions.

SUBMITTER: Zhao Y 

PROVIDER: S-EPMC7935544 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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A 3D Silverton-Type Polyoxomolybdate Based on {PrMo<sub>12</sub>O<sub>42</sub>}: Synthesis, Structure, Photoluminescence and Magnetic Properties.

Zhao Yanxin Y   Sun Xiaopeng X   Ji Yanfang Y   Kong Hui H   Chen Shumin S   Ma Pengtao P   Niu Jingyang J   Wang Jingping J  

Frontiers in chemistry 20210219


A three-dimensional (3D) Silverton-type polyoxomolybdate (POMo) with the formula of NH<sub>4</sub>{Mn<sub>4</sub>[PrMo<sub>12</sub>O<sub>42</sub>]}·18H<sub>2</sub>O (1) was successfully isolated and well characterized by single crystal X-ray diffraction, X-ray powder diffraction pattern, infrared spectrum, thermogravimetric and elemental analyses. The inorganic building block {PrMo<sub>12</sub>O<sub>42</sub>} has formed 3D frameworks <i>via</i> the {MnO<sub>6</sub>} linker. The excitation of com  ...[more]

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