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A facile calcination conversion of groundwater treatment sludge (GTS) as magnetic adsorbent for oxytetracycline adsorption.

ABSTRACT: In this paper, groundwater treatment sludge (GTS) was recycled as a magnetic adsorbent via a facile calcination process without adding any reductant. The prepared magnetic adsorbents (MAs) were characterized by scanning electron microscopy (SEM), X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS), vibrating sample magnenometer (VSM) and Mössbauer spectroscopy. The results showed that GTS comprised 33.2% Fe, 1.4% Al and 6.2% Si, and exhibited a weak saturation magnetization of 0.0008 emu/g. Without NaOH, the GTS calcinated at 700 and 500 °C were well magnetized with Ms of 20.1 and 7.1 emu/g, separately, but exhibited a low Ms of 0.43 emu/g at 300 °C. By adding NaOH powder, the Ms of GTS apparently increased to 4.9 emu/g after calcination at 300 °C, and further to 8.5 emu/g at 500 °C. In GTS, about 96.1% Fe was involved in ferrihydrite form. The Ms of calcinated GTS was accompanied with the phase transformation of ferrihydrite to maghemite. Si/Al oxides in GTS coordinated on the surface sites of ferrihydrite and inhibited the conjunction and phase transformation of adjacent ferrihydrite particles, but were effectively desorbed as in the presence of NaOH. Na500, preparing by calcinating GTS at 500 °C with NaOH, showed an optimal total surface sites (H_s) of 0.65 mmol/g. Oxytetracycline (OTC) was used as a target for studying the adsorption characteristics of synthetic magnetic adsorbents and a high adsorption capacity of oxytetracycline of 862.1 mg/g in comparison with the other calcinated GTS, and the adsorption data was consistent with the Langmuir model. By adding 6 g/L Na-500, approximately 100% of oxytetracycline and tetracycline and nearly 40% total organic carbon were removed from real pharmaceutical wastewater. With the method, GTS can be converted in mass production to magnetic adsorbent that exhibits effective application in pharmaceutical wastewater treatment.

SUBMITTER: Khan A

PROVIDER: S-EPMC7935931 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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A facile calcination conversion of groundwater treatment sludge (GTS) as magnetic adsorbent for oxytetracycline adsorption.

Khan Asghar A Huo Yang Y Qu Zhan Z Liu Yanwen Y Wang Zhihua Z Chen Yu Y Huo Mingxin M

Scientific reports 20210305 1

In this paper, groundwater treatment sludge (GTS) was recycled as a magnetic adsorbent via a facile calcination process without adding any reductant. The prepared magnetic adsorbents (MAs) were characterized by scanning electron microscopy (SEM), X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS), vibrating sample magnenometer (VSM) and Mössbauer spectroscopy. The results showed that GTS comprised 33.2% Fe, 1.4% Al and 6.2% Si, and exhibited a weak saturation magnetization of ...[more]

PMID: 33674650

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Project description:With increasing awareness of reduction of energy and CO2 footprint, more waste is considered recyclable for generating value-added products. Here we reported the negatively-valued iron mud, a waste from groundwater treatment plant, was successfully converted into magnetic adsorbent. Comparing with the conventional calcination method under the high temperature and pressure, the synthesis of the magnetic particles (MPs) by Fe2+/Fe3+ coprecipitation was conducted at environment-friendly condition using ascorbic acid (H2A) as reduction reagent and nitric acid (or acid wastewater) as leaching solution. The MPs with major component of Fe3O4 were synthesized at the molar ratio (called ratio subsequently) of H2A to Fe3+ of iron mud ≥ 0.1; while amorphous ferrihydrite phase was formed at the ratio ≤ 0.05, which were confirmed by vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). With the ratio increased, the crystalline size and the crystallization degree of MPs increased, and thus the Brunauer-Emmett-Teller (BET) surface and the cation-exchange capacity (CEC) decreased. MPs-3 prepared with H2A to Fe3+ ratio of 0.1 demonstrated the highest methylene blue (MB) adsorption of 87.3 mg/g and good magnetic response. The adsorption of MB onto MPs agreed well with the non-linear Langmuir isotherm model and the pseudo-second-order model. Pilot-scale experiment showed that 99% of MB was removed by adding 10 g/L of MPs-3. After five adsorption-desorption cycles, MPs-3 still showed 62% removal efficiency for MB adsorption. When nitric acid was replaced by acid wastewater from a propylene plant, the synthesized MPs-3w showed 3.7 emu/g of saturation magnetization (Ms) and 56.7 mg/g of MB adsorption capacity, 2.8 times of the widely used commercial adsorbent of granular active carbon (GAC). The major mechanism of MPs adsorption for MB was electrostatic attraction and cation exchange. This study synthesized a magnetic adsorbent from the negatively-valued iron mud waste by using an environment-friendly coprecipitation method, which had a potential for treatment of dye wastewater.

Dataset Information

A facile calcination conversion of groundwater treatment sludge (GTS) as magnetic adsorbent for oxytetracycline adsorption.

Publications

A facile calcination conversion of groundwater treatment sludge (GTS) as magnetic adsorbent for oxytetracycline adsorption.

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