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Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers.


ABSTRACT: New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoinduced cationic polymerization was investigated, and the PFPAE-based copolymer properties were thoroughly characterized. Interesting surface properties and two different values of refractive index were observed: thus, these fluorinated copolymers can be suitable materials for the manufacture of self-cleaning coatings and optical waveguides.

SUBMITTER: Trusiano G 

PROVIDER: S-EPMC7952294 | biostudies-literature |

REPOSITORIES: biostudies-literature

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