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Spin-state-dependent electrical conductivity in single-walled carbon nanotubes encapsulating spin-crossover molecules.

ABSTRACT: Spin crossover (SCO) molecules are promising nanoscale magnetic switches due to their ability to modify their spin state under several stimuli. However, SCO systems face several bottlenecks when downscaling into nanoscale spintronic devices: their instability at the nanoscale, their insulating character and the lack of control when positioning nanocrystals in nanodevices. Here we show the encapsulation of robust Fe-based SCO molecules within the 1D cavities of single-walled carbon nanotubes (SWCNT). We find that the SCO mechanism endures encapsulation and positioning of individual heterostructures in nanoscale transistors. The SCO switch in the guest molecules triggers a large conductance bistability through the host SWCNT. Moreover, the SCO transition shifts to higher temperatures and displays hysteresis cycles, and thus memory effect, not present in crystalline samples. Our results demonstrate how encapsulation in SWCNTs provides the backbone for the readout and positioning of SCO molecules into nanodevices, and can also help to tune their magnetic properties at the nanoscale.

SUBMITTER: Villalva J

PROVIDER: S-EPMC7952721 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Simple Method to Improve Electrical Conductivity of Films Made from Single-Walled Carbon Nanotubes.

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| S-EPMC8921219 | biostudies-literature

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| S-EPMC6523666 | biostudies-literature

The Dispersion State of Tangled Multi-Walled Carbon Nanotubes Affects Their Cytotoxicity.

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| S-EPMC5245756 | biostudies-literature

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Project description:We employ photoluminescence and pump-probe spectroscopy on films of semiconducting single-walled carbon nanotubes (CNTs) of different chirality wrapped with either a wide band gap polyfluorene derivative (PF12) or a polythiophene with narrower gap (P3DDT) to elucidate the excited states' interplay between the two materials. Excitation above the polymer band gap gives way to an ultrafast electron transfer from both polymers toward the CNTs. By monitoring the hole polaron on the polymer via its mid infrared signature, we show that also illumination below the polymer band gap leads to the formation of this fingerprint and infer that holes are also transferred toward the polymer. As this contradicts the standard way of discussing the involved energy levels, we propose that polymer-wrapped CNTs should be considered as a single hybrid system, exhibiting states shared between the two components. This proposition is validated through quantum chemical calculations that show hybridization of the first excited states, especially for the thiophene-CNT sample.

| S-EPMC5694966 | biostudies-literature

Temperature Distribution and Thermal Conductivity Measurements of Chirality-Assigned Single-Walled Carbon Nanotubes by Photoluminescence Imaging Spectroscopy.

Project description:It is expected that single-walled carbon nanotubes (SWCNTs) have high thermal conductivity along the tube axis and that the thermal conductivities depend on their structure, such as length, diameter, chirality (n, m), and so forth. Although many experimental measurements of the thermal conductivity have been reported, the SWCNT structure was not characterized sufficiently. In particular, the chirality was not assigned, and it was not confirmed whether SWCNT was isolated or not (bundled with multiplicate SWCNTs). Therefore, measured values widely vary (101 to 104 W/(m·K)) so far. Here, we measured the thermal conductivity of chirality-assigned SWCNTs, which were individually suspended, by using photoluminescence (PL) imaging spectroscopy. The temperature distribution along the tube axis was obtained, and the temperature dependence of the thermal conductivity was measured in a wide-temperature range (from 350 to 1000 K). For (9, 8) SWCNTs with 10-12 μm in length, the thermal conductivity was 1166 ± 243 W/(m·K) at 400 K. The proposed PL imaging spectroscopy enables to measure the thermal conductivity of SWCNTs with high precision and without any contacts, and it is an effective method in the temperature distribution measurements of nanomaterials.

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| S-EPMC7077723 | biostudies-literature

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