Ontology highlight
ABSTRACT:
SUBMITTER: Zhao G
PROVIDER: S-EPMC7988686 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20210119 4
Excited-state catalysis, a process that involves one or more excited catalytic species, has emerged as a powerful tool in organic synthesis because it allows access to the excited-state reaction landscape for the discovery of novel chemical reactivity. Herein, we report the first excited-state palladium-catalyzed 1,2-spin-center shift reaction that enables site-selective functionalization of carbohydrates. The strategy features mild reaction conditions with high levels of regio- and stereoselect ...[more]