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Inferring Changes in Summertime Surface Ozone-NO_x-VOC Chemistry over U.S. Urban Areas from Two Decades of Satellite and Ground-Based Observations.

ABSTRACT: Urban ozone (O₃) formation can be limited by NO_x, VOCs, or both, complicating the design of effective O₃ abatement plans. A satellite-retrieved ratio of formaldehyde to NO₂ (HCHO/NO₂), developed from theory and modeling, has previously been used to indicate O₃ formation chemistry. Here, we connect this space-based indicator to spatiotemporal variations in O₃ recorded by on-the-ground monitors over major U.S. cities. High-O₃ events vary nonlinearly with OMI HCHO and NO₂, and the transition from VOC-limited to NO_x-limited O₃ formation regimes occurs at higher HCHO/NO₂ value (3 to 4) than previously determined from models, with slight intercity variations. To extend satellite records back to 1996, we develop an approach to harmonize observations from GOME and SCIAMACHY that accounts for differences in spatial resolution and overpass time. Two-decade (1996-2016) multisatellite HCHO/NO₂ captures the timing and location of the transition from VOC-limited to NO_x-limited O₃ production regimes in major U.S. cities, which aligns with the observed long-term changes in urban-rural gradient of O₃ and the reversal of O₃ weekend effect. Our findings suggest promise for applying space-based HCHO/NO₂ to interpret local O₃ chemistry, particularly with the new-generation satellite instruments that offer finer spatial and temporal resolution.

SUBMITTER: Jin X

PROVIDER: S-EPMC7996126 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The World Health Organization (WHO) declared the coronavirus disease of 2019 (COVID-19) as a pandemic due to its widespread global infection. This has resulted in lockdown under different phases in many nations, including India, around the globe. In the present study, we report the impact of aerosols on surface ozone in the context of pre-lockdown (01st - 24th March 2020 (PLD)), lockdown phase1 (25th March to 14th April 2020 (LDP1)), and lockdown phase 2 (15th April to 03rd May 2020 (LDP2)) on clear days at a semi-arid site, Anantapur in southern India using both in situ observations and model simulations. Collocated measurements of surface ozone (O3), aerosol optical depth (AOD), black carbon mass concentration (BC), total columnar ozone (TCO), solar radiation (SR), and ultraviolet radiation (UV-A) data were collected using an Ozone analyzer, MICROTOPS sunphotometer, Ozonometer, Aethalometer, and net radiometer during the study period. The diurnal variations of O3 and BC exhibited an opposite trend during three phases. The concentrations of ozone were ~10.7% higher during LDP1 (44.8 ± 5.2 ppbv) than the PLD (40.5 ± 6.0 ppbv), which mainly due to an unprecedented reduction in NOx emissions leading to a lower O3 titration by NO. The prominent increase in the surface zone during LDP1 is reasonably consistent with the observed photolysis frequencies (j (O1D)) through Tropospheric Ultraviolet and Visible (TUV) model. The results show that a pronounced spectral and temporal variability in the AOD during three lockdown phases is mainly due to distinct aerosol sources. The increase in AOD during LDP2 due to long-range transport can bring large amounts of mineral dust and smoke aerosols from the west Asian region and central India, and which is reasonably consistent with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) air mass back trajectories and Moderate Resolution Imaging Spectroradiometer (MODIS) fire counts analysis over the measurement location. Overall, a drastic reduction in BC concentration (~8.4%) and AOD (10.8%) were observed in the semi-arid area during LDP1 with correspondence to PLD. The columnar aerosol size distributions retrieved from the spectral AODs followed power-law plus unimodal during three phases. The absorption angstrom exponent (AAE) analysis reveals a predominant contribution to the BC from biomass burning activities during the lockdown period over the measurement location.

Project description:IntroductionAmbient air pollution is associated with premature death caused by heart disease, stroke, chronic obstructive pulmonary disease (COPD), and lung cancer. Recent studies have suggested that ribonucleic acid (RNA) oxidation is a sensitive environment-related biomarker that is implicated in pathogenesis.Aims and methodsWe used a novel approach that integrated RNA-Seq analysis with detection by immunoprecipitation techniques of the prominent RNA oxidative modification 8-oxo-7,8-dihydroguanine (8-oxoG). Our goal was to uncover specific messenger RNA (mRNA) oxidation induced by mixtures of volatile organic compounds (VOCs) and ozone in healthy human epithelial lung cells. To this end, we exposed the BEAS-2B human epithelial lung cell line to the gas- and particle-phase products formed from reactions of 790 ppb acrolein (ACR) and 670 ppb methacrolein (MACR) with 4 ppm ozone.ResultsUsing this approach, we identified 222 potential direct targets of oxidation belonging to previously described pathways, as well as uncharacterized pathways, after air pollution exposures. We demonstrated the effect of our VOC-ozone mixtures on the morphology and actin cytoskeleton of lung cells, suggesting the influence of selective mRNA oxidation in members of pathways regulating physical components of the cells. In addition, we observed the influence of the VOC-ozone mixtures on metabolic cholesterol synthesis, likely implicated as a result of the incidence of mRNA oxidation and the deregulation of protein levels of squalene synthase (farnesyl-diphosphate farnesyltransferase 1 [FDFT1]), a key enzyme in endogenous cholesterol biosynthesis.ConclusionsOverall, our findings indicate that air pollution influences the accumulation of 8-oxoG in transcripts of epithelial lung cells that largely belong to stress-induced signaling and metabolic and structural pathways. A strength of the study was that it combined traditional transcriptome analysis with transcriptome-wide 8-oxoG mapping to facilitate the discovery of underlying processes not characterized by earlier approaches. Investigation of the processes mediated by air pollution oxidation of RNA molecules in primary cells and animal models needs to be explored in future studies. Our research has thus opened new avenues to further inform the relationship between atmospheric agents on the one hand and cellular responses on the other that are implicated in diseases.

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Inferring Changes in Summertime Surface Ozone-NO_x-VOC Chemistry over U.S. Urban Areas from Two Decades of Satellite and Ground-Based Observations.

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Inferring Changes in Summertime Surface Ozone-NOx-VOC Chemistry over U.S. Urban Areas from Two Decades of Satellite and Ground-Based Observations.

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OmicsDI is part of the ELIXIR infrastructure

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Inferring Changes in Summertime Surface Ozone-NO_x-VOC Chemistry over U.S. Urban Areas from Two Decades of Satellite and Ground-Based Observations.