Browse
Submit Data
Databases
API
Help

Dataset Information

30 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Photocatalytic Activity of Cellulose Acetate Nanoceria/Pt Hybrid Mats Driven by Visible Light Irradiation

ABSTRACT: A photocatalytic system for the degradation of aqueous organic pollutants under visible light irradiation is obtained by an innovative approach based on ceria/platinum (Pt) hybrid nanoclusters on cellulose acetate fibrous membranes. The catalytic materials are fabricated by supersonic beam deposition of Pt nanoclusters directly on the surface of electrospun cellulose acetate fibrous mats, pre-loaded with a cerium salt precursor that is transformed into ceria nanoparticles directly in the solid mats by a simple thermal treatment. The presence of Pt enhances the oxygen vacancies on the surface of the formed ceria nanoparticles and reduces their band gap, resulting in a significant improvement of the photocatalytic performance of the composite mats under visible light irradiation. Upon the appropriate pretreatment and visible light irradiation, we prove that the most efficient mats, with both ceria nanoparticles and Pt nanoclusters, present a degradation efficiency of methylene blue of 70% and a photodegradation rate improved by about five times compared to the ceria loaded samples, without Pt. The present results bring a significant improvement of the photocatalytic performance of polymeric nanocomposite fibrous systems under visible light irradiation, for efficient wastewater treatment applications.

SUBMITTER: Costantino F

PROVIDER: S-EPMC8002269 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Super Water-Repellent Cellulose Acetate Mats.

Project description:A single-step synthesis of super-water-repellent oil sorbents based on cellulose acetate (CA) mats is reported in this paper. Key phenomenological mechanisms involving roughness and changes in chemistry are used to describe the change in hydrophobic behavior of the CA mats. Contact angle calculations followed by Cassie's model apparent contact angle prediction have shown roughness alone is not capable of producing the super-hydrophobicity exhibited by as-spun mats. Fourier transform infrared spectroscopy of spin coated and electrospun mats shows a significant difference in the stretching of the hydroxyl bonds of the two materials. As it is this hydroxyl group which adds to the overall polarity of surface thus hydrophilicity of the material, we propose that the electrospinning process not only creates a rougher surface but also alters the chemistry of the electrospun cellulose acetate mats which ultimately gives rise to the reported hydrophobicity. Finally, due to their water repellent nature, and oleophilicity of the as-spun mats were tested as oil sorbent mats. The as-spun mats were capable of absorbing thirty times their weight in oil demonstrating their application for oil-water remediation.

| S-EPMC6102242 | biostudies-literature

Efficient Photocatalytic Disinfection of Escherichia coli O157:H7 using C70-TiO2 Hybrid under Visible Light Irradiation.

Project description:Efficient photocatalytic disinfection of Escherichia coli O157:H7 was achieved by using a C70 modified TiO2 (C70-TiO2) hybrid as a photocatalyst under visible light (λ > 420 nm) irradiation. Disinfection experiments showed that 73% of E. coli O157:H7 died within 2 h with a disinfection rate constant of k = 0.01 min(-1), which is three times that measured for TiO2. The mechanism of cell death was investigated by using several scavengers combined with a partition system. The results revealed that diffusing hydroxyl radicals play an important role in the photocatalytically initiated bacterial death, and direct contact between C70-TiO2 hybrid and bacteria is not indispensable in the photocatalytic disinfection process. Extracellular polymeric substances (EPS) of bacteria have little effect on the disinfection efficiency. Analyses of the inhibitory effect of C70-TiO2 thin films on E. coli O157:H7 showed a decrease of the bacterial concentration from 3 × 10(8) to 38 cfu mL(-1) in the solution with C70-TiO2 thin film in the first 2 h of irradiation and a complete inhibition of the growth of E. coli O157:H7 in the later 24 h irradiation.

| S-EPMC4861983 | biostudies-literature

Bioactive Cellulose Acetate Electrospun Mats as Scaffolds for Bone Tissue Regeneration.

Project description:In the last decades, cell-based approaches for bone tissue engineering (BTE) have relied on using models that cannot replicate the complexity of the bone microenvironment. There is an ongoing amount of research on scaffold development responding to the need for feasible materials that can mimic the bone extracellular matrix (ECM) and aid bone tissue regeneration (BTR). In this work, a porous cellulose acetate (CA) fiber mat was developed using the electrospinning technique and the mats were chemically modified to bioactivate their surface and promote osteoconduction and osteoinduction. The mats were characterized using FTIR and SEM/EDS to validate the chemical modifications and assess their structural integrity. By coupling adhesive peptides KRSR, RGD, and growth factor BMP-2, the fiber mats were bioactivated, and their induced biological responses were evaluated by employing immunocytochemical (ICC) techniques to study the adhesion, proliferation, and differentiation of premature osteoblast cells (hFOB 1.19). The biological assessment revealed that at short culturing periods of 48 hours and 7 days, the presence of the peptides was significant for proliferation and adhesion, whereas at longer culture times of 14 days, it had no significant effect on differentiation and maturation of the osteogenic progenitor cells. Based on the obtained results, it is thus concluded that the CA porous fiber mats provide a promising surface morphology that is both biocompatible and can be rendered bioactive upon the addition of osteogenic peptides to favor osteoconduction leading to new tissue formation.

| S-EPMC8837436 | biostudies-literature

Photocatalytic Water Splitting for O₂ Production under Visible Light Irradiation Using NdVO₄-V₂O₅ Hybrid Powders.

Project description:The study investigated photocatalytic water splitting for O₂ production under visible light irradiation using neodymium vanadium oxide (NdVO₄) and vanadium oxide (V₂O₅) hybrid powders. The results in a sacrificial agent of 0.01 M AgNO₃ solution were obtained, and the highest photocatalytic O₂ evolution was 2.63 μmol/h, when the hybrid powders were prepared by mixing Nd and V at a volume ratio of 1:3 at a calcination temperature of 350 °C for 1 h. The hybrid powders were synthesized by neodymium nitrate and ammonium metavanadate using the glycothermal method in ethylene glycol at 120 °C for 1 h. The hybrid powders consisted of two shapes, NdVO₄ nanoparticles and the cylindrical V₂O₅ particles, and they possessed the ability for photocatalytic oxygen (O₂) evolution during irradiation with visible light. The band gaps and structures of the hybrid powders were analyzed using UV-visible spectroscopy and transmission electron microscopy.

| S-EPMC5506984 | biostudies-other

Biofabricated BiOI with enhanced photocatalytic activity under visible light irradiation.

Project description:In the recent past, there has been a large-scale utilization of plant extracts for the synthesis of various photocatalysts. The biofabrication technology eliminates the usage of harmful chemicals and serves as an eco-friendly approach for environmental remediation. Herein, a comparative analysis between bismuth oxyiodide synthesized via Azadirachta indica (neem) leaf extract (BiOI-G) and without leaf extract (BiOI-C) has been envisaged. The BiOI-G and BiOI-C samples were characterized by spectral and microscopic techniques, which revealed that the Azadirachta indica assisted BiOI-G attained enhanced features over BiOI-C such as narrower band gap, large surface area, porosity, increased absorption range of visible light and effectual splitting of the photogenerated e--h+ pairs. Benefiting from these enhanced features, BiOI-G degraded methyl orange (MO), rhodamine B (RhB), and benzotriazole (BT) at a significantly higher rate in comparison to BiOI-C. The degradation rate of MO, RhB and BT by BiOI-G was observed to be 1.3, 1.25 and 1.29 times higher in comparison to BiOI-C. Moreover, BiOI-G displayed high stability upto five cycles of the photocatalytic activity, which endow its effectiveness as a highly-efficient green photocatalyst.

| S-EPMC9084558 | biostudies-literature

Photocatalytic Simultaneous Removal of Nitrite and Ammonia via a Zinc Ferrite/Activated Carbon Hybrid Catalyst under UV-Visible Irradiation.

Project description:Nitrite and ammonia often coexist in waters. Thus, it is very significant to develop a photocatalytic process for the simultaneous removal of nitrite and ammonia. Herein, zinc ferrite/activated carbon (ZnFe2O4/AC) was synthesized and characterized by X-ray diffraction spectroscopy, transmission electron microscopy, Raman spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. The valence band level of ZnFe2O4 was measured by X-ray photoelectron spectroscopy-valence band spectroscopy, and first-principles calculation was performed to confirm the band structure of ZnFe2O4. The as-synthesized ZnFe2O4/AC species functioned as a photocatalyst to simultaneously remove nitrite and ammonia under anaerobic conditions upon UV-visible light irradiation at the first stage. The results indicated that an average removal ratio of 92.7% with ±0.2% error for nitrite degradation for three runs was achieved in 50.0 mg/L nitrite + 100.0 mg/L ammonia solution with pH 9.5 under anaerobic conditions for 3 h at this stage; simultaneously, the removal ratio of 64.0% with ±0.2% error for ammonia was also achieved. At the second stage, oxygen gas was bubbled in the reactor to photocatalytically eliminate residual ammonia under aerobic conditions upon continuous irradiation. The results demonstrated that the removal ratios for nitrite, ammonia, and total nitrogen reached to 92.0, 90.0, and 90.2% at 12th hour, respectively, and the product released during photocatalysis is N2 gas, detected by gas chromatography, fulfilling the simultaneous removal of nitrite and ammonia. The reaction mechanism was exploited.

| S-EPMC6648888 | biostudies-literature

Photocatalytic surface patterning of cellulose using diazonium salts and visible light.

Project description:Coumarin-functionalized cellulose sheets were chemically modified using a visible light catalyzed "Photo-Meerwein" arylation. Use of a photomask to pattern the surface resulted in directly visible images.

| S-EPMC3830929 | biostudies-literature

Visible-Light-Driven Photocatalytic Activity of Magnetic BiOBr/SrFe12O19 Nanosheets.

Project description:Magnetic BiOBr/SrFe12O19 nanosheets were successfully synthesized using the hydrothermal method. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and UV-visible diffused reflectance spectra (UV-DRS), and the magnetic properties were tested using a vibration sample magnetometer (VSM). The as-produced composite with an irregular flaky-shaped aggregate possesses a good anti-demagnetization ability (Hc = 861.04 G) and a high photocatalytic efficiency. Under visible light (λ > 420 nm) and UV light-emitting diode (LED) irradiation, the photodegradation rates of Rhodamine B (RhB) using BiOBr/SrFe12O19 (5 wt %) (BOB/SFO-5) after 30 min of reaction were 97% and 98%, respectively, which were higher than that using BiOBr (87%). The degradation rate of RhB using the recovered BiOBr/5 wt % SrFe12O19 (marked as BOB/SFO-5) was still more than 85% in the fifth cycle, indicating the high stability of the composite catalyst. Meanwhile, after five cycles, the magnetic properties were still as stable as before. The radical-capture experiments proved that superoxide radicals and holes were main active species in the photocatalytic degradation of RhB.

| S-EPMC6567020 | biostudies-literature

Enhanced Photocatalytic Fuel Denitrification over TiO2/?-Fe2O3 Nanocomposites under Visible Light Irradiation.

Project description:With increasingly stringent environmental regulations, the removal of nitrogen-containing compounds (NCCs) from gasoline fuel has become a more and more important research subject. In this work, we have successfully synthesized TiO2/?-Fe2O3 heterogeneous photocatalysts with different mass ratios of TiO2 vs. ?-Fe2O3. Taking photocatalytic denitrification of typical alkali NCCs, pyridine, in gasoline fuel under visible light irradiation (????420?nm) as the model reaction, the TiO2/?-Fe2O3 hybrids have exhibited enhanced photocatalytic activity compared with pure TiO2 and ?-Fe2O3, giving a pyridine removal ratio of ?100% after irradiation for 240?min. The improved photocatalytic performance can be attributed to the integrative effect of the enhanced light absorption intensity and more efficient separation of photogenerated electron-hole pairs. Importantly, this type of heterogeneous photocatalysts can be easily separate in the reaction medium by an external magnetic field that is very important for industrial purpose. In addition, major reaction intermediates have been identified by the liquid chromatograph-mass spectrometer (HPLC-MS) and a tentative photocatalytic denitrification mechanism has been proposed.

| S-EPMC5552819 | biostudies-other

Hybrid BiOBr/UiO-66-NH<sub>2</sub> composite with enhanced visible-light driven photocatalytic activity toward RhB dye degradation.

Project description:Metal-organic framework (MOFs) based composites have received more research interest for photocatalytic applications during recent years. In this work, a highly active, visible light photocatalyst BiOBr/UiO-66-NH2 hybrid composite was successfully prepared by introducing various amounts of UiO-66-NH2 with BiOBr through a co-precipitation method. The composites were applied for the photocatalytic degradation of RhB (rhodamine B) dye. The developed BiOBr/UiO-66-NH2 composites exhibited higher photocatalytic activity than the pristine material. In RhB degradation experiments the hybrid composite with 15 wt% of UiO-66-NH2 shows degradation efficiency conversion of 83% within two hours under visible light irradiation. The high photodegradation efficiency of BUN-15 could be ascribed to efficient interfacial charge transfer at the heterojunction and the synergistic effect between BiOBr/UiO-66-NH2. In addition, an active species trapping experiment confirmed that photo-generated hole+ and O2 - radicals are the major species involved in RhB degradation under visible light.

| S-EPMC9077208 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data