A Facile Solution Engineering of PEDOT:PSS-Coated Conductive Textiles for Wearable Heater Applications
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ABSTRACT:
SUBMITTER: Jin I
PROVIDER: S-EPMC8003570 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:The conductive polymer complex poly (3,4-ethylene dioxythiophene):polystyrene sulfonate (PEDOT:PSS) is the most explored conductive polymer for conductive textiles applications. Since PEDOT:PSS is readily available in water dispersion form, it is convenient for roll-to-roll processing which is compatible with the current textile processing applications. In this work, we have made a comprehensive review on the PEDOT:PSS-based conductive textiles, methods of application onto textiles and their applications. The conductivity of PEDOT:PSS can be enhanced by several orders of magnitude using processing agents. However, neat PEDOT:PSS lacks flexibility and strechability for wearable electronics applications. One way to improve the mechanical flexibility of conductive polymers is making a composite with commodity polymers such as polyurethane which have high flexibility and stretchability. The conductive polymer composites also increase attachment of the conductive polymer to the textile, thereby increasing durability to washing and mechanical actions. Pure PEDOT:PSS conductive fibers have been produced by solution spinning or electrospinning methods. Application of PEDOT:PSS can be carried out by polymerization of the monomer on the fabric, coating/dyeing and printing methods. PEDOT:PSS-based conductive textiles have been used for the development of sensors, actuators, antenna, interconnections, energy harvesting, and storage devices. In this review, the application methods of PEDOT:SS-based conductive polymers in/on to a textile substrate structure and their application thereof are discussed.
| S-EPMC7180874 | biostudies-literature
Project description:Durable, electrically conducting yarns are a critical component of electronic textiles (e-textiles). Here, such yarns with exceptional wear and wash resistance are realized through dyeing silk from the silkworm Bombyx mori with the conjugated polymer:polyelectrolyte complex PEDOT:PSS. A high Young's modulus of approximately 2 GPa combined with a robust and scalable dyeing process results in up to 40 m long yarns that maintain their bulk electrical conductivity of approximately 14 S cm-1 when experiencing repeated bending stress as well as mechanical wear during sewing. Moreover, a high degree of ambient stability is paired with the ability to withstand both machine washing and dry cleaning. For the potential use for e-textile applications to be illustrated, an in-plane thermoelectric module that comprises 26 p-type legs is demonstrated by embroidery of dyed silk yarns onto a piece of felted wool fabric.
| S-EPMC5355901 | biostudies-literature
Project description:Bioelectricity drives several processes in the human body. The development of new materials that can deliver electrical stimuli is gaining increasing attention in the field of tissue engineering. In this work, novel, highly electrically conductive nanofibers made of poly [2,2'-m-(phenylene)-5,5'-bibenzimidazole] (PBI) have been manufactured by electrospinning and then coated with cross-linked poly (3,4-ethylenedioxythiophene) doped with poly (styrene sulfonic acid) (PEDOT:PSS) by spin coating or dip coating. These scaffolds have been characterized by scanning electron microscopy (SEM) imaging and attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy. The electrical conductivity was measured by the four-probe method at values of 28.3 S·m-1 for spin coated fibers and 147 S·m-1 for dip coated samples, which correspond, respectively, to an increase of about 105 and 106 times in relation to the electrical conductivity of PBI fibers. Human bone marrow-derived mesenchymal stromal cells (hBM-MSCs) cultured on the produced scaffolds for one week showed high viability, typical morphology and proliferative capacity, as demonstrated by calcein fluorescence staining, 4',6-diamidino-2-phenylindole (DAPI)/Phalloidin staining and MTT [3-(4,5-dimethylthiazol-2-yl)-2,5 diphenyl tetrazolium bromide] assay. Therefore, all fiber samples demonstrated biocompatibility. Overall, our findings highlight the great potential of PEDOT:PSS-coated PBI electrospun scaffolds for a wide variety of biomedical applications, including their use as reliable in vitro models to study pathologies and the development of strategies for the regeneration of electroactive tissues or in the design of new electrodes for in vivo electrical stimulation protocols.
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Project description:Flexible sensors are fundamental devices for human body monitoring. The mechanical strain and physiological parameters coupled sensing have attracted increasing interest in this field. However, integration of different sensors in one platform usually involves complex fabrication process-flows. Simplification, even if essential, remains a challenge. Here, we investigate a piezoresistive and electrochemical active electrospun nanofibers (NFs) mat as the sensitive element of the wearable physiological flex sensing platform. The use of one material sensitive to the two kinds of stimuli reduces the process-flow to two steps. We demonstrate that the final NFs pH-Flex Sensor can be used to monitor the deformation of a human body joint as well as the pH of the skin. A unique approach has been selected for pH sensing, based on Electrochemical Impedance Spectroscopy (EIS). A linear dependence of the both the double layer capacitance and charge transfer re-sistance with the pH value was obtained by EIS, as well as a linear trend of the electrical resistance with the bending deformation. Gauge factors values calculated after the bending test were 45.84 in traction and 208.55 in compression mode, reflecting the extraordinary piezoresistive behavior of our nanostructured NFs.
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Project description:Superhydrophobic surfaces are bioinspired, nanotechnology artifacts, which feature a reduced friction coefficient, whereby they can be used for a number of very practical applications including, on the medical side, the manipulation of biological solutions. In this work, we integrated superhydrophobic patterns with the conducting polymer PEDOT:PSS, one of the most used polymers in organic electronics because highly sensitive to ionized species in solution. In doing so, we combined geometry and materials science to obtain an advanced device where, on account of the superhydrophobicity of the system, the solutions of interest can be manipulated and, on account of the conductive PEDOT:PSS polymer, the charged molecules dispersed inside can be quantitatively measured. This original substrate preparation allowed to perform electrochemical measurements on ionized species in solution with decreasing concentration down to 10(-7) molar. Moreover, it was demonstrated the ability of the device of realizing specific, combined time and space resolved analysis of the sample. Collectively, these results demonstrate how a tight, interweaving integration of different disciplines can provide realistic tools for the detection of pathologies. The scheme here introduced offers breakthrough capabilities that are expected to radically improve both the pace and the productivity of biomedical research, creating an access revolution.
| S-EPMC3919119 | biostudies-literature
Project description:This paper presents the formulation, inkjet printing, and vacuum forming of a conductive and stretchable polymer, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), ink on a stretchable and transparent thermoplastic polyurethane (TPU) substrate. The formulation of the conductive and stretchable ink is achieved by combining PEDOT:PSS with additional solvents, to achieve the right inkjet properties for drop-on-demand (DoD) inkjet printing. A conductive pattern can be printed from the 21 µm orifice on a flexible and stretchable TPU substrate, with a linewidth down to 44 µm. The properties of the printed pattern, in terms of sheet resistance, morphology, transparency, impact of weather conditions, and stretching are investigated and show sheet resistances up to 45 Ohm/sq and transparencies as high as 95%, which is comparable to indium tin oxide (ITO). Moreover, in contrast to ITO, one-time stretching up to 40% can be achieved, increasing the sheet resistance up to 214 Ohm/sq only, showing the great potential of this ink for one-time stretching. Finally, as a proof of this one-time stretching, the printed samples are vacuum formed around a 3D object, still showing sufficient conductivity to be applied as a capacitive touch sensor.
| S-EPMC7762030 | biostudies-literature
Project description:We present a simple thermoelectric device that consists of a conductive poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)-based inorganic/organic thermoelectric film with high thermoelectric performance. The PEDOT:PSS-coated Se NWs were first chemically synthesized in situ, and then mixed with an Ag precursor solution to produce the PEDOT:PSS-coated Ag2Se NWs. The PEDOT:PSS matrix was then treated with dimethyl sulfoxide (DMSO) prior to the production of flexible PEDOT:PSS-coated Ag2Se NW/PEDOT:PSS composite films with various weight fractions of Ag2Se via a simple drop-casting method. The thermoelectric properties (Seebeck coefficient, electrical conductivity, and power factor) of the composite films were then analyzed. The composite film with 50 wt.% NWs exhibited the highest power factor of 327.15 μW/m·K2 at room temperature. The excellent flexibility of this composite film was verified by bending tests, in which the thermoelectric properties were reduced by only ~5.9% after 1000 bending cycles. Finally, a simple thermoelectric device consisting of five strips of the proposed composite film was constructed and was shown to generate a voltage of 7.6 mV when the temperature difference was 20 K. Thus, the present study demonstrates that that the combination of a chalcogenide and a conductive composite film can produce a high-performance flexible thermoelectric composite film.
| S-EPMC7826913 | biostudies-literature
Project description:We synthesized a hybrid nanocomposite comprised of selenium nanoparticles coated with a thin layer of a conductive polymer, poly(3,4-ethylenedioxythiophene), and studied its thermoelectric properties. The conductive polymer layer on the surface of nanoparticles in the composites formed a percolating network running between the stacked nanoparticles, exhibiting an electrical conductivity close to or higher than that of pure polymer. The thermoelectric power factor of the resulting composite was higher than that of individual polymer or selenium nanoparticles. We further increased the electrical conductivity of the composite by thermal annealing, thereby improving the power factor to 15 μW/cmK2 which is nine times higher than that of the polymer.
| S-EPMC6631964 | biostudies-literature
Project description:In this paper, we report the fabrication of highly conductive poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)/cellulose nanofiber (CNF) nanocomposite paper with excellent flexibility through post-treatment with an organic solvent. The post-treated PEDOT:PSS/CNF porous nanocomposite papers showed a lower sulfur content, indicating the removal of residual PSS. The electrical conductivity of PEDOT:PSS/CNF porous nanocomposite paper was increased from 1.05 S/cm to 123.37 S/cm and 106.6 S/cm by post-treatment with dimethyl sulfoxide (DMSO) and ethylene glycol (EG), respectively. These values are outstanding in the development of electrically conductive CNF composites. Additionally, the highly conductive nanocomposite papers showed excellent bending stability during bending tests. Cyclic voltammetry (CV) showed a Faradaic redox reaction and non-Faradaic capacitance due to the redox activity of PEDOT:PSS and large surface area, respectively. Electrochemical energy storage ability was evaluated and results showed that capacitance improved after post-treatment. We believe that the highly conductive PEDOT:PSS/CNF porous nanocomposite papers with excellent flexibility described here are potential candidates for application in porous paper electrodes, flexible energy storage devices, and bioengineering sensors.
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Project description:The inhomogeneity of the resistance of conducting polypyrrole-coated nylon-Lycra and polyester (PET) fabrics and its effects on surface temperature were investigated through a systematic experimental and numerical work including the optimization of coating conditions to determine the lowest resistivity conductive fabrics and establish a correlation between the fabrication conditions and the efficiency and uniformity of Joule heating in conductive textiles. For this purpose, the effects of plasma pre-treatment and molar concentration analysis of the dopant anthraquinone sulfonic acid (AQSA), oxidant ferric chloride, and monomer pyrrole was carried out to establish the conditions to determine the sample with the lowest electrical resistance for generating heat and model the experiments using the finite element modeling (FEM). Both PET and nylon-Lycra underwent atmospheric plasma treatment to functionalize the fabric surface to improve the binding of the polymer and obtain coatings with reduced resistance. Both fabrics were compared in terms of average electrical resistance for both plasma treated and untreated samples. The plasma treatment induced deep black coatings with lower resistance. Then, heat-generating experiments were conducted on the polypyrrole (PPy) coated fabrics with the lowest resistance using a variable power supply to study the distribution and maximum value of the temperature. The joule heating model was developed to predict the heating of the conductive fabrics via finite element analysis. The model was based on the measured electrical resistance at different zones of the coated fabrics. It was shown that, when the fabric was backed with neoprene insulation, it would heat up quicker and more evenly. The average electrical resistance of the PPy-PET sample used was 190 Ω, and a maximum temperature reading of 43 °C was recorded. The model results exhibited good agreement with thermal camera data.
| S-EPMC7865377 | biostudies-literature