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Crystallographic characterization of (C5H4SiMe3)3U(BH4).


ABSTRACT: New syntheses have been developed for the synthesis of (borohydrido-κ3 H)tris-[η5-(tri-methyl-sil-yl)cyclo-penta-dien-yl]uranium(IV), [U(BH4)(C8H13Si)3] or Cp'3U(BH4) (Cp' = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P and the structure features three η 5-coordinated Cp' rings and a κ 3-coordinated (BH4)- ligand.

SUBMITTER: Windorff CJ 

PROVIDER: S-EPMC8025856 | biostudies-literature |

REPOSITORIES: biostudies-literature

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