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First crystal structure of a Pigment Red 52 compound: DMSO solvate hydrate of the monosodium salt.

ABSTRACT: Pigment Red 52, Na₂[C₁₈H₁₁ClN₂O₆S], is an industrially produced hydrazone-laked pigment. It serves as an inter-mediate in the synthesis of the corresponding Ca²⁺ and Mn²⁺ salts, which are used commercially for printing inks and lacquers. Hitherto, no crystal structure of any salt of Pigment Red 52 is known. Now, single crystals have been obtained of a dimethyl sulfoxide solvate hydrate of the monosodium salt of Pigment Red 52, namely, monosodium 2-[2-(3-carb-oxy-2-oxo-1,2-di-hydro-naphthalen-1-yl-idene)hydrazin-1-yl]-5-chloro-4-methyl-benz-ene-sulfonate dimethyl sulfoxide monosolvate monohydrate, Na⁺·C₁₈H₁₂ClN₂O₆S^-·H₂O·C₂H₆OS, obtained from in-house synthesized Pigment Red 52. The crystal structure was determined by single-crystal X-ray diffraction at 173 K. In this monosodium salt, the SO₃ ^- group is deprotonated, whereas the COOH group is protonated. The residues form chains via ionic inter-actions and hydrogen bonds. The chains are arranged in polar/non-polar double layers.

SUBMITTER: Tapmeyer L

PROVIDER: S-EPMC8025858 | biostudies-literature |

REPOSITORIES: biostudies-literature

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