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Synthesis, crystal structure and thermal properties of poly[bis-[μ2-3-(amino-meth-yl)pyridine]-bis-(thio-cyanato)-cobalt(II)].

ABSTRACT: The reaction of Co(NCS)2 with 3-(amino-meth-yl)pyridine as coligand leads to the formation of crystals of the title compound, [Co(NCS)2(C6H8N2)2] n , that were characterized by single-crystal X-ray analysis. In the crystal structure, the CoII cations are octa-hedrally coordinated by two terminal N-bonded thio-cyanate anions as well as two pyridine and two amino N atoms of four symmetry-equivalent 3-(amino-meth-yl)pyridine coligands with all pairs of equivalent atoms in a trans position. The CoII cations are linked by the 3-(amino-meth-yl)pyridine coligands into layers parallel to the ac plane. These layers are further linked by inter-molecular N-H⋯S hydrogen bonding into a three-dimensional network. The purity of the title compound was determined by X-ray powder diffraction and its thermal behavior was investigated by differential scanning calorimetry and thermogravimetry.

SUBMITTER: Krebs C 

PROVIDER: S-EPMC8025872 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Synthesis, crystal structure and thermal properties of poly[bis-[μ<sub>2</sub>-3-(amino-meth-yl)pyridine]-bis-(thio-cyanato)-cobalt(II)].

Krebs Christoph C   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Crystallographic communications 20210326 Pt 4

The reaction of Co(NCS)<sub>2</sub> with 3-(amino-meth-yl)pyridine as coligand leads to the formation of crystals of the title compound, [Co(NCS)<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>N<sub>2</sub>)<sub>2</sub>] <sub><i>n</i></sub> , that were characterized by single-crystal X-ray analysis. In the crystal structure, the Co<sup>II</sup> cations are octa-hedrally coordinated by two terminal N-bonded thio-cyanate anions as well as two pyridine and two amino N atoms of four symmetry-equivalent 3-(am  ...[more]

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