Browse
Submit Data
Databases
API
Help

Dataset Information

20 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Circularly polarized luminescence from organic micro-/nano-structures.

ABSTRACT: Circularly polarized light exhibits promising applications in future displays and photonic technologies. Circularly polarized luminescence (CPL) from chiral luminophores is an ideal approach to directly generating circularly polarized light, in which the energy loss induced by the circularly polarized filters can be reduced. Among various chiral luminophores, organic micro-/nano-structures have attracted increasing attention owing to the high quantum efficiency and luminescence dissymmetry factor. Herein, the recent progress of CPL from organic micro-/nano-structures is summarized. Firstly, the design principles of CPL-active organic micro-/nano-structures are expounded from the construction of micro-/nano-structure and the introduction of chirality. Based on these design principles, several typical organic micro-/nano-structures with CPL activity are introduced in detail, including self-assembly of small molecules, self-assembly of π-conjugated polymers, and self-assembly on micro-/nanoscale architectures. Subsequently, we discuss the external stimuli that can regulate CPL performance, including solvents, pH value, metal ions, mechanical force, and temperature. We also summarize the applications of CPL-active materials in organic light-emitting diodes, optical information processing, and chemical and biological sensing. Finally, the current challenges and prospects in this emerging field are presented. It is expected that this review will provide a guide for the design of excellent CPL-active materials.

SUBMITTER: Deng Y

PROVIDER: S-EPMC8039044 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Mechano-responsive circularly polarized luminescence of organic solid-state chiral emitters.

Project description:Two difluoro-boron ?-diketonate complexes bearing chiral amido groups have been synthesized. Their mechano-responsive luminescence and chiroptical properties have been investigated in the solid state. Both compounds display a bright blue-green emission and a significant circularly polarized luminescence (CPL) signal in the crystalline state, with |g lum| values as high as 2.2-2.4 × 10-2. A bathochromic shift in emission, together with a decrease of |g lum| values to c.a. 3 × 10-3, is induced upon application of a shearing stress. For the DFB-Hex-amide compound, interestingly, sign inversion of the anisotropy factor g lum is observed under mechanical stimulation ("mechano-CPL effect"), which can be rationalized by a switching between monomer and excimer emission.

| S-EPMC6345345 | biostudies-literature

Boosting Circularly Polarized Luminescence of Organic Conjugated Systems via Twisted Intramolecular Charge Transfer.

Project description:Realizing a high luminescence dissymmetry factor (g lum) is a paramount yet challenging issue in the research field of circularly polarized luminescence (CPL). Here, we reported a novel set of organic conjugated systems with twisted intramolecular charge transfer (TICT) characteristics based on conjugated o-carborane-binaphthyl dyads composing of binaphthyl units as chiral electron donors and o-carborane units as achiral electron acceptors, demonstrating intense CPL with large g lum values. Interestingly, single-crystalline o-1 exhibited a high-level brightness and a large g lum factor as high as +0.13, whereas single-crystalline o-2 processed a relatively low brightness with a decreased g lum value to -0.04. The significant diversity of CPL-active properties was triggered by the selective introduction of o-carborane units onto the binaphthyl units. Benefiting from the large magnetic dipole transition moments in TICT states, the CPL activity of TICT o-carborane-based materials exhibited amplified circular polarization. This study provides an efficient molecular engineering strategy for the rational design and development of highly efficient CPL-active materials.

| S-EPMC7193308 | biostudies-literature

Dual-Mode Induction of Tunable Circularly Polarized Luminescence from Chiral Metal-Organic Frameworks.

Project description:The general approach for fabricating solid-state materials showing circularly polarized luminescence (CPL) is still in its challenge. In this work, chiral metal-organic frameworks (MOFs) with full-color and white-color circularly polarized light emission are firstly achieved through a host-guest emitter-loading strategy. Chiral zeolitic imidazolate frameworks (ZIFs, a class of MOFs) are fabricated by a facile and simple mixed-ligand coassembly pathway. Meantime, achiral dyes, quantum dots (QDs), and upconversion nanoparticles (UCNPs) are easily loaded into the chiral ZIFs during the synthetic process. Size-matched dyes can be solely encapsulated into the chiral cages of ZIF, resulting in induced CPL and enhanced luminescence efficiency in solid-state ZIF⊃dye composites. Large-sized QDs, after embedding into the gap of the ZIF particles, also exhibited intense CPL activity. Furthermore, through modulating the blending ratio of colored dyes or QDs in chiral ZIFs, white light-emitting ZIFs with circular polarization could be constructed in a solid state. In addition, through loading rare earth element-based upconversion nanoparticles (UCNPs) into chiral ZIFs, upconverted CPL (UC-CPL) could be achieved with a high dissymmetry factor (g lum). Thus, various achiral luminophores were endowed with CPL upon coupling with chiral ZIFs, which significantly deepened and enlarged the research scope of the chiroptical materials in a solid state.

| S-EPMC6998039 | biostudies-literature

Bis(haloBODIPYs) with Labile Helicity: Valuable Simple Organic Molecules That Enable Circularly Polarized Luminescence.

Project description:Simple organic molecules (SOM) based on bis(haloBODIPY) are shown to enable circularly polarized luminescence (CPL), giving rise to a new structural design for technologically valuable CPL-SOMs. The established design comprises together synthetic accessibility, labile helicity, possibility of reversing the handedness of the circularly polarized emission, and reactive functional groups, making it unique and attractive as advantageous platform for the development of smart CPL-SOMs.

| S-EPMC5060947 | biostudies-literature

A [2]Rotaxane-Based Circularly Polarized Luminescence Switch.

Project description:A rotaxane-based molecular shuttle has been synthesized in which the switching of the position of a fluorescent macrocycle on the thread turns "on" or "off" the circularly polarized luminescence (CPL) of the system while maintaining similar fluorescence profiles and quantum yields in both states. The chiroptical activity relies on the chiral information transfer from an ammonium salt incorporating d- or l-phenylalanine residues as chiral stereogenic covalent units to an otherwise achiral crown ether macrocycle bearing a luminescent 2,2'-bipyrene unit when they interact through hydrogen bonding. Each enantiomeric thread induces CPL responses of opposite signs on the macrocycle. Upon addition of base, the switching of the position of the macrocycle to a triazolium group disables the chiral information transfer to the macrocycle, switching "off" the CPL response. The in situ switching upon several acid/base cycles is also demonstrated.

| S-EPMC6975276 | biostudies-literature

Sequentially amplified circularly polarized ultraviolet luminescence for enantioselective photopolymerization.

Project description:Chiral optical materials based on circularly polarized luminescence (CPL) have emerged rapidly due to their feasible applications in diverse fields of research. However, limited to the small luminescence dissymmetry factor (glum), real application examples have rarely been reported. Here, we present a complex system, which show intense circularly polarized ultraviolet luminescence (CPUVL) with large glum value, enabling a chiral UV light triggered enantioselective polymerization. By integrating sensitized triplet-triplet annihilation upconversion and CPL, both visible-to-UV upconversion emission and upconverted circularly polarized ultraviolet luminescence (UC-CPUVL) were obtained in the systems, built of chiral annihilator R(S)-4,12-biphenyl[2,2]paracyclophane (R-/S-TP), and a thermally activated delayed fluorescence (TADF) sensitizer. After dispersing this upconversion system into room-temperature nematic liquid crystal, induced chiral nematic liquid crystal could significantly amplify the glum value (0.19) of UC-CPUVL. Further, the UC-CPUVL emission has been used to trigger the enantioselective photopolymerization of diacetylene. This work paves the way for the further development of functional application of CPL active materials.

| S-EPMC7652877 | biostudies-literature

Boosting the circularly polarized luminescence of small organic molecules <i>via</i> multi-dimensional morphology control.

Project description:Achieving a higher dissymmetry factor is a crucial issue in developing circularly polarized luminescence (CPL) materials. Here, by tailoring the solvent composition and the morphology of the same chiral emissive small molecules (R- or S-SPAn), circularly polarized emission with a boosted dissymmetry factor (two orders) was realized. It was found that by regulating the water fraction in the mixed THF/H2O, we were able to achieve kinetic control over association of chiral emissive R- or S-SPAn into various nanostructures with 0D nanospheres, 2D nanoflakes and 3D stacked nanoflakes. These nanostructures are all CPL active. Remarkably, the dissymmetry factors of the nanostructures were significantly enhanced compared to those of the molecules and further boosted in different morphologies, from ∼10-4 (0D nanospheres) to 10-3 (2D flake) to ∼10-2 (3D nanoflakes). The enlarged g lum value could be assigned to a good packing induced strong luminescence of an excimer. This strategy provides an efficient way to fabricate higher dissymmetry factor CPL organic nanomaterials by only changing the supramolecular architectures while using the same chiral small molecules.

| S-EPMC6657416 | biostudies-literature

Manipulating the Assembly of Au Nanoclusters for Luminescence Enhancement and Circularly Polarized Luminescence

Project description:Au nanocluster (AuNCs)-based luminescent functional materials have attracted the interest of researchers owing to their small size, tractable surface modification, phosphorescence lifetime and biocompatibility. However, the poor luminescence quantum yield (QY) of AuNCs limits their practical applications. Herein, we synthesized a type of AuNCs modified by 4,6-diamino-2-mercaptopyrimidine hydrate (DPT-AuNCs). Furthermore, organic acids, i.e., citric acid (CA) and tartaric acid (TA), were chosen for co-assembly with DPT-AuNCs to produce AuNCs-based luminescent materials with enhanced emission. Firstly, it was found that CA could significantly enhance the emission of DPT−AuNCs with the formation of red emission nanofibers (QY = 17.31%), which showed a potential for usage in I− detection. The n···π/π···π interaction between the CA and the DPT ligand was proposed as crucial for the emission. Moreover, chiral TA could not only improve the emission of DPT-AuNCs, but could also transfer its chirality to DPT-AuNCs and induce the formation of circularly polarized luminescence (CPL)-active nanofibers. It was demonstrated that the CPL signal could increase 4.6-fold in a ternary CA/TA/DPT-AuNCs co-assembly system. This work provides a convenient way to build AuNCs-based luminescent materials as probes, and opens a new avenue for building CPL-active materials by achiral NCs through a co-assembly strategy.

| S-EPMC9101361 | biostudies-literature

Acid/base-triggered switching of circularly polarized luminescence and electronic circular dichroism in organic and organometallic helicenes.

Project description:Electronic circular dichroism and circularly polarized luminescence acid/base switching activity has been demonstrated in helicene-bipyridine proligand 1?a and in its "rollover" cycloplatinated derivative 2?a. Whereas proligand 1?a displays a strong bathochromic shift (>160?nm) of the nonpolarized and circularly polarized luminescence upon protonation, complex 2?a displays slightly stronger emission. This strikingly different behavior between singlet emission in the organic helicene and triplet emission in the organometallic derivative has been rationalized by using quantum-chemical calculations. The very large bathochromic shift of the emission observed upon protonation of azahelicene-bipyridine 1?a has been attributed to the decrease in aromaticity (promoting a charge-transfer-type transition rather than a ?-?* transition) as well as an increase in the HOMO-LUMO character of the transition and stabilization of the LUMO level upon protonation.

| S-EPMC4801116 | biostudies-literature

A chemosensor-based chiral coassembly with switchable circularly polarized luminescence.

Project description:Fluorescent chemosensors represent fast response to analytes with pronounced luminescent variations. They are promising as potential candidates in controlling luminescence and chiroptical activities of self-assembled chiral systems, which however have not been accomplished to date. We present a coassembled multiple component system that could respond to SO2 derivatives, giving rise to dynamic aggregation behaviors and switchable luminescence as well as circularly polarized luminescence (CPL). Cholesteryl-naphthalimide and coumarin derivatives coassemble into vesicles and nanohelices under the solvent strategy, behaving as energy transfer donor and accepter respectively. Energy transfer enables CPL transition from green to red depending on the molar fraction. After the addition of SO2 derivatives, hypochromic shifts occur to CPL due to the nucleophilic addition reaction to coumarin domain, hindering energy transfer and allow for the emergence of pristine luminescence. Here, we show a protocol to control over luminescence and chiroptical features of supramolecular chiral self-assemblies using fluorescent chemosensors.

| S-EPMC8566482 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data