Unknown

Dataset Information

0

α-Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1-(Dialkylamino)-1,2,3-triazoles.


ABSTRACT: The one-pot synthesis of a series of sulfonium salts containing transferable diazomethyl groups is described, and the structure of these compounds is elucidated by X-ray crystallography. Under photochemical conditions, reaction of these salts with N,N-dialkyl hydrazones affords 1-(dialkylamino)-1,2,3-triazoles via diazomethyl radical addition to the azomethine carbon followed by intramolecular ring closure. The straightforward transformation of the structures thus obtained into mesoionic carbene-metal complexes is also reported and the donor properties of these new ligands characterized.

SUBMITTER: Li X 

PROVIDER: S-EPMC8048477 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC3543115 | biostudies-literature
| S-EPMC4382718 | biostudies-literature
| S-EPMC5798646 | biostudies-literature
| S-EPMC2982995 | biostudies-literature
| S-EPMC6648081 | biostudies-literature
| S-EPMC2946857 | biostudies-literature
| S-EPMC8949195 | biostudies-literature
| S-EPMC3224852 | biostudies-literature
| S-EPMC10235848 | biostudies-literature
| S-EPMC9146814 | biostudies-literature