Unknown

Dataset Information

0

Synthesis, crystal structure and Hirshfeld surface analysis of [bis-(di-phenyl-phosphan-yl)methane-κP]chloridobis-[2-(pyridin-2-yl)phenyl-κ2 N,C 1]iridium(III).

ABSTRACT: The title IrIII complex, [Ir(C11H8N)2Cl(C25H22P2)], was synthesized from the substitution reaction between the (ppy)2Ir(μ-Cl)2Ir(ppy)2 (ppy = deprotonated 2-phenyl-pyridine, C11H8N-) dimer and 1,1-bis-(di-phenyl-phosphan-yl)methane (dppm, C25H22P2) under an argon gas atmosphere for 20 h. The IrIII atom is coordinated by two C,N-bidentate ppy anions, a unidentate dppm ligand and a chloride anion in a distorted octa-hedral IrC2N2PCl arrangement. The N donor atoms of the ppy ligands are mutually trans while the C atoms are cis. Intra-molecular aromatic π-π stacking between the phenyl rings of ppy and dppm, and C-H⋯Cl inter-actions are observed. In the crystal, C-H⋯Cl and C-H⋯π contacts link the mol-ecules into a three-dimensional network. A Hirshfeld surface analysis was carried out to further qu-antify the inter-molecular inter-actions, and indicated that H⋯H contacts (63.9%) dominate the packing.

SUBMITTER: Klaimanee E 

PROVIDER: S-EPMC8061097 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis, crystal structure and Hirshfeld surface analysis of [bis-(di-phenyl-phosphan-yl)methane-κ<i>P</i>]chloridobis-[2-(pyridin-2-yl)phenyl-κ<sup>2</sup> <i>N</i>,<i>C</i> <sup>1</sup>]iridium(III).

Klaimanee Ekkapong E   Sangwisut Peerapong P   Saithong Saowanit S   Leesakul Nararak N  

Acta crystallographica. Section E, Crystallographic communications 20210202 Pt 3

The title Ir<sup>III</sup> complex, [Ir(C<sub>11</sub>H<sub>8</sub>N)<sub>2</sub>Cl(C<sub>25</sub>H<sub>22</sub>P<sub>2</sub>)], was synthesized from the substitution reaction between the (ppy)<sub>2</sub>Ir(μ-Cl)<sub>2</sub>Ir(ppy)<sub>2</sub> (ppy = deprotonated 2-phenyl-pyridine, C<sub>11</sub>H<sub>8</sub>N<sup>-</sup>) dimer and 1,1-bis-(di-phenyl-phosphan-yl)methane (dppm, C<sub>25</sub>H<sub>22</sub>P<sub>2</sub>) under an argon gas atmosphere for 20 h. The Ir<sup>III</sup> atom is coordi  ...[more]

Similar Datasets

Unknown (Acetonitrile-κN)chloridobis[2-(pyridin-2-yl)phenyl-κC,N]iridium(III).
| S-EPMC3238736 | biostudies-literature
Unknown Crystal structure of {(E)-2-[(phenyl-imino)-meth-yl]phenolato-κ(2) N,O}bis-[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) di-chloro-methane monosolvate.
| S-EPMC4908569 | biostudies-literature
Unknown Crystal structure of <i>fac</i>-[2-(4-methyl-5-phenyl-pyridin-2-yl)phenyl-κ<sup>2</sup><i>C</i><sup>1</sup>,<i>N</i>]bis-[2-(pyridin-2-yl)phenyl-κ<sup>2</sup><i>C</i><sup>1</sup>,<i>N</i>]iridium(III).
| S-EPMC5137604 | biostudies-literature
Unknown Crystal structure of <i>fac</i>-{5-[(hexyl-aza-nium-yl)meth-yl]-2-(pyridin-2-yl)phenyl-κ<sup>2</sup> <i>N</i>,<i>C</i> <sup>1</sup>}bis-[2-(pyridin-2-yl)phenyl-κ<sup>2</sup> <i>N</i>,<i>C</i> <sup>1</sup>]iridium(III) chloride.
| S-EPMC6176433 | biostudies-literature
Unknown (4-Chloro-acetanilido-κ(2)N,O)bis-[2-(pyridin-2-yl)phenyl-κ(2)C(1),N]iridium(III).
| S-EPMC3569196 | biostudies-literature
Unknown (Pyridine-2-aldoximato-κ(2) N,N')bis-[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III).
| S-EPMC3588427 | biostudies-literature
Unknown <i>trans</i>-Bis[bis-(di-phenyl-phosphan-yl)methane-κ<sup>2</sup><i>P</i>,<i>P</i>']di-chlorido-ruthenium(II): a triclinic polymorph.
| S-EPMC10833132 | biostudies-literature
Unknown Crystal structure of <i>mer</i>-tris-{2,6-di-fluoro-3-[5-(2-fluoro-phen-yl)pyridin-2-yl-κ<i>N</i>]pyridin-4-yl-κ<i>C</i><sup>4</sup>}iridium(III) di-chloro-methane hemisolvate <i>n</i>-hexane hemisolvate.
| S-EPMC5730259 | biostudies-literature
Unknown Crystal structure of {(E)-2-[(3,4-di-meth-oxy-phenyl-imino)-meth-yl]phenolato-κ2N,O1}bis-[2-(pyridin-2-yl)phenyl-κ2C1,N]iridium(III) di-chloro-methane disolvate.
| S-EPMC6072996 | biostudies-literature
Unknown Crystal structure and luminescent properties of bis-[2,6-dimethyl-3-(pyridin-2-yl-κ<i>N</i>)pyridin-4-yl-κ<i>C</i><sup>4</sup>](2,2,6,6-tetra-methylhepta-ne-3,5-dionato-κ<sup>2</sup><i>O</i>,<i>O</i>')iridium(III) ethyl acetate monosolvate.
| S-EPMC6127711 | biostudies-literature