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Structural investigation of N-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]benzamide and N-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]-4-meth-oxy-benzamide.

ABSTRACT: The compound N-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]benzamide, C21H16FN3O3S, crystallizes in the monoclinic centrosymmetric space group P21/c and its mol-ecular conformation is stabilized via an intra-molecular N-H⋯O hydrogen bond. The corresponding para-meth-oxy derivative, namely, N-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]-4-meth-oxy-benzamide, C22H18FN3O4S, crystallizes in the monoclinic centrosymmetric space group C2/c. The supra-molecular network mainly comprises N-H⋯O, N-H⋯S and C-H⋯O hydrogen bonds, which contribute towards the formation of the crystal structures for the two mol-ecules. The different inter-molecular inter-actions have been further analysed using Hirshfeld surface analysis and fingerprint plots.

SUBMITTER: Dey D 

PROVIDER: S-EPMC8061111 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Structural investigation of <i>N</i>-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]benzamide and <i>N</i>-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]-4-meth-oxy-benzamide.

Dey Dhananjay D   Shruti I I   Chopra Deepak D   Mohan T P TP  

Acta crystallographica. Section E, Crystallographic communications 20210219 Pt 3

The compound <i>N</i>-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]benzamide, C<sub>21</sub>H<sub>16</sub>FN<sub>3</sub>O<sub>3</sub>S, crystallizes in the monoclinic centrosymmetric space group <i>P</i>2<sub>1</sub>/<i>c</i> and its mol-ecular conformation is stabilized <i>via</i> an intra-molecular N-H⋯O hydrogen bond. The corresponding <i>para</i>-meth-oxy derivative, namely, <i>N</i>-[2-(4-fluoro-3-phen-oxy-benzo-yl)hydrazinecarbo-thio-yl]-4-meth-oxy-benzamide, C<sub>22</sub>H<sub  ...[more]

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