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Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO₂: Promising Waste-Derived Adsorbents for Balofloxacin.

ABSTRACT: Biochars (BC) of spent coffee grounds, both pristine (SCBC) and impregnated with titanium oxide (TiO₂@SCBC) were exploited as environmentally friendly and economical sorbents for the fluroquinolone antibiotic balofloxacin (BALX). Surface morphology, functional moieties, and thermal stabilities of both adsorbents were scrutinized using SEM, EDS, TEM, BET, FTIR, Raman, and TG/dT analyses. BET analysis indicated that the impregnation with TiO₂ has increased the surface area (50.54 m²/g) and decreased the pore size and volume. Batch adsorption experiments were completed in lights of the experimental set-up of Plackett-Burman design (PBD). Two responses were maximized; the % removal (%R) and the adsorption capacity (q_e, mg/g) as a function of four variables: pH, adsorbent dosage (AD), BALX concentration ([BALX]), and contact time (CT). %R of 68.34% and 91.78% were accomplished using the pristine and TiO₂@SCBC, respectively. Equilibrium isotherms indicated that Freundlich model was of a perfect fit for adsorption of BALX onto both adsorbents. Maximum adsorption capacity (q_max) of 142.55 mg/g for SCBC and 196.73 mg/g for the TiO₂@SCBC. Kinetics of the adsorption process were best demonstrated using the pseudo-second order (PSO) model. The adsorption-desorption studies showed that both adsorbents could be restored with the adsorption efficiency being conserved up to 66.32% after the fifth cycles.

SUBMITTER: El-Azazy M

PROVIDER: S-EPMC8071459 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Torrefaction of biomass is a promising thermochemical pretreatment technique used to upgrade the properties of biomass to produce solid fuel with improved fuel properties. A comparative study of the effects of torrefaction temperatures (200, 250, and 300 °C) and residence times (0.5 and 1 h) on the quality of torrefied biomass samples derived from spent coffee grounds (SCG) and coffee husk (CH) were conducted. An increase in torrefaction temperature (200-300 °C) and residence time (0.5-1 h) for CH led to an improvement in the fixed carbon content (17.9-31.8 wt %), calorific value (18.3-25 MJ/kg), and carbon content (48.5-61.2 wt %). Similarly, the fixed carbon content, calorific value, and carbon content of SCG rose by 14.6-29 wt %, 22.3-30.3 MJ/kg, and 50-69.5 wt %, respectively, with increasing temperature and residence time. Moreover, torrefaction led to an improvement in the hydrophobicity and specific surface area of CH and SCG. The H/C and O/C atomic ratios for both CH- and SCG-derived torrefied biomass samples were in the range of 0.93-1.0 and 0.19-0.20, respectively. Moreover, a significant increase in volatile compound yield was observed at temperatures between 250 and 300 °C. Maximum volatile compound yields of 11.9 and 6.2 wt % were obtained for CH and SCG, respectively. A comprehensive torrefaction model for CH and SCG developed in Aspen Plus provided information on the mass and energy flows and the overall process energy efficiency. Based on the modeling results, it was observed that with increasing torrefaction temperature to 300 °C, the mass and energy yield values of the torrefied biomass samples declined remarkably (97.3% at 250 °C to 67.5% at 300 °C for CH and 96.7% at 250 °C to 75.1% at 300 °C for SCG). The SCG-derived torrefied biomass tested for CO2 adsorption at 25 °C had a comparatively higher adsorption capacity of 0.38 mmol/g owing to its better textural characteristics. SCG would need further thermal treatment or functionalization to tailor the surface properties to attract more CO2 molecules under a typical post-combustion scenario.

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Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO₂: Promising Waste-Derived Adsorbents for Balofloxacin.

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Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO2: Promising Waste-Derived Adsorbents for Balofloxacin.

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OmicsDI is part of the ELIXIR infrastructure

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Biochar of Spent Coffee Grounds as Per Se and Impregnated with TiO₂: Promising Waste-Derived Adsorbents for Balofloxacin.