Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules.

ABSTRACT: Based on solvothermal synthesis, self-assembly of the heptadentate 2,6-diacetylpyridine bis(nicotinoylhydrazone) Schiff base ligand (H₂L) and Zn(II) and/or Cd(II) salts has led to the formation of three homometallic [CdL]_n (1), {[CdL]∙0.5dmf∙H₂O}_n (2) and {[ZnL]∙0.5dmf∙1.5H₂O}_n (3), as well as two heterometallic {[Zn_0.75Cd_1.25L₂]∙dmf∙0.5H₂O}_n (4) and {[MnZnL₂]∙dmf∙3H₂O}_n coordination polymers. Compound 1 represents a 1D chain, whereas 2-5 are isostructural and isomorphous two-dimensional structures. The entire series was characterized by IR spectroscopy, thermogravimetric analysis, single-crystal X-ray diffraction and emission measurements. 2D coordination polymers accommodate water and dmf molecules in their cage-shaped interlayer spaces, which are released when the samples are heated. Thus, three solvated crystals were degassed at two temperatures and their photoluminescent and adsorption-desorption properties were recorded in order to validate this assumption. Solvent-free samples reveal an increase in volume pore, adsorption specific surface area and photoluminescence with regard to synthesized crystals.

SUBMITTER: Danilescu O 

PROVIDER: S-EPMC8073138 | biostudies-literature |

REPOSITORIES: biostudies-literature