Ambient ozone pollution at a coal chemical industry city in the border of Loess Plateau and Mu Us Desert: characteristics, sensitivity analysis and control strategies.

ABSTRACT: In this study, ambient ozone (O₃) pollution characteristics and sensitivity analysis were carried out in Yulin, a city in the central area of the Loess Plateau during 2017 to 2019 summer. O₃ concentrations increased for 2017 to 2019. Correlation and statistics analysis indicated high temperature (T > 25 °C, low relative humidity (RH < 60%), and low wind speed (WS < 3 m/s) were favorable for O₃ formation and accumulation, and the O₃ pollution days (MDA8 O₃ > 160 µg/m³) were predominantly observed when the wind was traveling from the easterly and southerly. O₃ concentration in urban area of Yulin was higher than that in background. The pollution air masses from Fenwei Plain increase the level and duration of O₃ pollution. In order to clarify the formation mechanism and source of O₃, online measurements of volatile organic compounds (VOCs) were conducted from 7 July to 10 August in 2019. The average of VOCs concentration was 26 ± 12 ppbv, and large amounts of alkenes followed by aromatics, characteristic pollutants of the coal chemical industry, were detected in the ambient air. To further measure the sensitivity, the observation-based model (OBM) simulation was conducted. Empirical Kinetic Modeling Approach (EKMA) plot and relative incremental reactivity (RIR) value indicated Yulin located on VOCs-limited regime. That implied a slight decrease of NO_x may increase O₃ concentration. When the emission reduction ratio of anthropogenic VOCs/NO_x higher than 1:1, the O₃ will decrease. O₃ control strategies analysis shows that the O₃ targets of 5% and 10% O₃ concentration reductions are achievable through precursor control, but more effort is needed to reach the 30% and 40% reduction control targets.

SUBMITTER: Yin M 

PROVIDER: S-EPMC8086580 | biostudies-literature |

REPOSITORIES: biostudies-literature