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Mol-ecular structure of fac-[Mo(CO)₃(DMSO)₃].

ABSTRACT: The title compound, tri-carbonyl-tris-(dimethyl sulfoxide)-molybdenum, [Mo(C₂H₆OS)₃(CO)₃] or fac-[Mo(CO)₃(DMSO)₃], crystallizes in the triclinic space group P with two mol-ecules in the unit cell. The geometry around the central molybdenum is slightly distorted octa-hedral and the facial isomer is found exclusively. The packing within the crystal is stabilized by three-dimensional non-classical inter-molecular hydrogen-bonding contacts between individual methyl substituents of di-methyl sulfoxide and the oxygen atoms of either another di-methyl sulfoxide or a carbonyl ligand on adjacent complex mol-ecules. The observed bond lengths in the carbonyl ligands and between carbonyl carbon atoms and molybdenum are correlated to the observed FT-IR bands for the carbonyl stretches and compared to respective metrical parameters of related complexes.

SUBMITTER: Elvers BJ

PROVIDER: S-EPMC8100265 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Crystal and mol-ecular structure of aflatrem.

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Crystal structure of (2R)-1-[(methyl-sulfon-yl)-oxy]propan-2-aminium chloride: a chiral mol-ecular salt.

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| S-EPMC4647372 | biostudies-literature