Browse
Submit Data
Databases
API
Help

Dataset Information

34 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Protein-assisted scalable mechanochemical exfoliation of few-layer biocompatible graphene nanosheets.

ABSTRACT: A facile method to produce few-layer graphene (FLG) nanosheets is developed using protein-assisted mechanical exfoliation. The predominant shear forces that are generated in a planetary ball mill facilitate the exfoliation of graphene layers from graphite flakes. The process employs a commonly known protein, bovine serum albumin (BSA), which not only acts as an effective exfoliation agent but also provides stability by preventing restacking of the graphene layers. The latter is demonstrated by the excellent long-term dispersibility of exfoliated graphene in an aqueous BSA solution, which exemplifies a common biological medium. The development of such potentially scalable and toxin-free methods is critical for producing cost-effective biocompatible graphene, enabling numerous possible biomedical and biological applications. A methodical study was performed to identify the effect of time and varying concentrations of BSA towards graphene exfoliation. The fabricated product has been characterized using Raman spectroscopy, powder X-ray diffraction, transmission electron microscopy and scanning electron microscopy. The BSA-FLG dispersion was then placed in media containing Astrocyte cells to check for cytotoxicity. It was found that lower concentrations of BSA-FLG dispersion had only minute cytotoxic effects on the Astrocyte cells.

SUBMITTER: Thomas DG

PROVIDER: S-EPMC8101280 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Interlayer catalytic exfoliation realizing scalable production of large-size pristine few-layer graphene.

Project description:Mass production of reduced graphene oxide and graphene nanoplatelets has recently been achieved. However, a great challenge still remains in realizing large-quantity and high-quality production of large-size thin few-layer graphene (FLG). Here, we create a novel route to solve the issue by employing one-time-only interlayer catalytic exfoliation (ICE) of salt-intercalated graphite. The typical FLG with a large lateral size of tens of microns and a thickness less than 2 nm have been obtained by a mild and durative ICE. The high-quality graphene layers preserve intact basal crystal planes owing to avoidance of the degradation reaction during both intercalation and ICE. Furthermore, we reveal that the high-quality FLG ensures a remarkable lithium-storage stability (>1,000 cycles) and a large reversible specific capacity (>600 mAh g(-1)). This simple and scalable technique acquiring high-quality FLG offers considerable potential for future realistic applications.

| S-EPMC3555088 | biostudies-other

Aqueous dispersions of few-layer-thick chemically modified magnesium diboride nanosheets by ultrasonication assisted exfoliation.

Project description:The discovery of graphene has led to a rising interest in seeking quasi two-dimensional allotropes of several elements and inorganic compounds. Boron, carbon's neighbour in the periodic table, presents a curious case in its ability to be structured as graphene. Although it cannot independently constitute a honeycomb planar structure, it forms a graphenic arrangement in association with electron-donor elements. This is exemplified in magnesium diboride (MgB2): an inorganic layered compound comprising boron honeycomb planes alternated by Mg atoms. Till date, MgB2 has been primarily researched for its superconducting properties; it hasn't been explored for the possibility of its exfoliation. Here we show that ultrasonication of MgB2 in water results in its exfoliation to yield few-layer-thick Mg-deficient hydroxyl-functionalized nanosheets. The hydroxyl groups enable an electrostatically stabilized aqueous dispersion and create a heterogeneity leading to an excitation wavelength dependent photoluminescence. These chemically modified MgB2 nanosheets exhibit an extremely small absorption coefficient of 2.9 ml mg(-1) cm(-1) compared to graphene and its analogs. This ability to exfoliate MgB2 to yield nanosheets with a chemically modified lattice and properties distinct from the parent material presents a fundamentally new perspective to the science of MgB2 and forms a first foundational step towards exfoliating metal borides.

| S-EPMC4603704 | biostudies-literature

Millstone Exfoliation: a True Shear Exfoliation for Large-Size Few-Layer Graphene Oxide.

Project description:A millstone (MS) was introduced in the production of large-size few-layer-graphene oxide (FLGO) via true shear exfoliation in order to minimize fragmentation. The MS was constructed with two glass plates, where the top plate was designed to rotate against the stationary bottom plate, thereby generating true shear force. Mildly oxidized graphite (MOG) was used for MS exfoliation in order to obtain both good property and high yield. The rpm of rotation (10, 20, 30, 40, and 50), solution concentration (0.5, 1, and 2 mg/ml), and number of exfoliation (1, 2, and 3) were optimized by measuring the UV-vis absorption, and the effect of oxidation time (30, 60, and 90 min) was studied under the given optimum conditions. Next, the FLGO was isolated by centrifugation and characterized by TEM and AFM. The FLGO obtained was as large as ~ 10 μm in size, which was slightly smaller than the pristine graphite, suggesting a possibility of slight fragmentation. But it was still much larger than the FLGO obtained via sonication (< 1 μm), demonstrating successful MS exfoliation.

| S-EPMC6010364 | biostudies-literature

Few-layer and large flake size borophene: preparation with solvothermal-assisted liquid phase exfoliation.

Project description:The preparation of two-dimensional boron (B) nanosheets, especially for borophene, is still a challenge because of its unique structure and complex B-B bonds in bulk boron. In the present work, a novel preparation technology for borophene with only a few layers and large flake sizes is developed by a solvothermal-assisted liquid phase exfoliation process, consisting of ball milling-thinning, solvothermal swelling, and probe ultrasonic delamination. The exfoliation effect of the bulk B precursors is related to the surface tension and Hildebrand parameter of the selected solvents such as acetone, N,N-dimethyl formamide (DMF), acetonitrile, ethanol, and N-methyl pyrrolidone (NMP), and a relative small surface tension when using solvents is favorable for the exfoliation of bulk B. Four-layer thick borophene and an average lateral size of 5.05 μm can be obtained in acetone as the exfoliating solvent. The surface composition of the exfoliated few-layer borophene with large flake size hardly changes, while the chemical state of B changes to some extent because they are partly oxidized on the surface by contaminates before and after exfoliation. This acetone solvothermal-assisted liquid phase exfoliation technique can be used to prepare high quality borophene with large horizontal sizes, and it will provide the basis to study few-layer borophene with large sizes further.

| S-EPMC9055579 | biostudies-literature

Few-Layer Antimonene by Liquid-Phase Exfoliation.

Project description:We report on a fast and simple method to produce highly stable isopropanol/water (4:1) suspensions of few-layer antimonene by liquid-phase exfoliation of antimony crystals in a process that is assisted by sonication but does not require the addition of any surfactant. This straightforward method generates dispersions of few-layer antimonene suitable for on-surface isolation. Analysis by atomic force microscopy, scanning transmission electron microscopy, and electron energy loss spectroscopy confirmed the formation of high-quality few-layer antimonene nanosheets with large lateral dimensions. These nanolayers are extremely stable under ambient conditions. Their Raman signals are strongly thickness-dependent, which was rationalized by means of density functional theory calculations.

| S-EPMC5113666 | biostudies-literature

Shear-Assisted Production of Few-Layer Boron Nitride Nanosheets by Supercritical CO<sub>2</sub> Exfoliation and Its Use for Thermally Conductive Epoxy Composites.

Project description:Boron nitride nanosheets (BNNS) hold the similar two-dimensional structure as graphene and unique properties complementary to graphene, which makes it attractive in application ranging from electronics to energy storage. The exfoliation of boron nitride (BN) still remains challenge and hinders the applications of BNNS. In this work, the preparation of BNNS has been realized by a shear-assisted supercritical CO2 exfoliation process, during which supercritical CO2 intercalates and diffuses between boron nitride layers, and then the exfoliation of BN layers is obtained in the rapid depressurization process by overcoming the van der Waals forces. Our results indicate that the bulk boron nitride has been successfully exfoliated into thin nanosheets with an average 6 layers. It is found that the produced BNNS is well-dispersed in isopropyl alcohol (IPA) with a higher extinction coefficient compared with the bulk BN. Moreover, the BNNS/epoxy composite used as thermal interface materials has been prepared. The introduction of BNNS results in a 313% enhancement in thermal conductivity. Our results demonstrate that BNNS produced by supercritical CO2 exfoliation show great potential applications for heat dissipation of high efficiency electronics.

| S-EPMC5736726 | biostudies-literature

Nanocomposite Hydrogels Containing Few-Layer Graphene Sheets Prepared through Noncovalent Exfoliation Show Improved Mechanical Properties.

Project description:Hydrogels show great potential as soft materials for biomedical applications and flexible devices. However, conventional hydrogels exhibit poor mechanical strengths owing to the presence of water in their polymer networks. Therefore, improving the mechanical properties of hydrogels by controlling the chemical and physical structures that affect their macroscopic behaviors is a challenging issue. In this study, we developed a nanocomposite (NC) hydrogel that harbors exfoliated few-layer graphene sheets through noncovalent interactions. The bifunctional polymer PImQ, which contains both aromatic and cationic groups, was found to enable the direct exfoliation of graphite to few-layer graphene through π-π interactions in 2.7% yield. The poly(acrylamide)-based NC hydrogel containing the PImQ/graphene composite as a nanofiller shows a 3.4-fold increase in tensile stress compared with the hydrogel without the nanofiller. The introduction of the PImQ/graphene nanocomposite also increases the fracture stress of the NC hydrogel through cation-π and π-π interactions. The improved mechanical properties of the NC hydrogel result from the synergistic effects of the chemical crosslinking of the polymer network and the physical crosslinking of the polymer/graphene nanofiller.

| S-EPMC9505845 | biostudies-literature

ZnO/Graphene Composite from Solvent-Exfoliated Few-Layer Graphene Nanosheets for Photocatalytic Dye Degradation under Sunlight Irradiation.

Project description:ZnO/graphene nanocomposites were prepared using a facile approach. Graphene nanosheets were prepared by ultrasonication-based liquid phase exfoliation of graphite powder in a low boiling point organic solvent, 1,2-Dichloroethane, for the preparation of ZnO/graphene nanocomposites. Structural properties of the synthesized ZnO/graphene nanocomposites were studied through powder XRD and micro-Raman analysis. The characteristic Raman active modes of ZnO and graphene present in the micro-Raman spectra ensured the formation of ZnO/graphene nanocomposite and it is inferred that the graphene sheets in the composites were few layers in nature. Increasing the concentration of graphene influenced the surface morphology of the ZnO nanoparticles and a flower shape ZnO was formed on the graphene nanosheets of the composite with high graphene concentration. The efficiencies of the samples for the photocatalytic degradation of Methylene Blue dye under sunlight irradiation were investigated and 97% degradation efficiency was observed. The stability of the nanocomposites was evaluated by performing five cycles, and 92% degradation efficiency was maintained. The observed results were compared with that of ZnO/graphene composite derived from other methods.

| S-EPMC9860591 | biostudies-literature

Green and facile synthesis of few-layer graphene via liquid exfoliation process for Lithium-ion batteries.

Project description:A green and facile method using jet cavitation (JC) was utilized to prepare few layer graphene (FLG) derived from artificial graphite delamination without adding any strong acids and oxidants. The JC method not only provides high quality FLG with high yield but also demonstrate excellent electrochemical performance as anode materials for Li-ion batteries. Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) as well as BET isotherms and XPS are carried out in this study. The results of atomic force microscopy (AFM) further revealed that up to 85% of the prepared FLG were less than 10 layers. This exfoliation process happened mainly due to the cavitation-induced intensive tensile stress acting on the layered materials. Electrochemical measurements demonstrate that graphite anode delivered only 240 mAh/g while FLG anode achieved more than 322 mAh/g at 5C rate test. These results indicate that JC method not only paves the way for cheaper and safer production of graphene but also holds great potential applications in energy-related technology.

| S-EPMC6021450 | biostudies-literature

Biocompatible, Electroconductive, and Highly Stretchable Hybrid Silicone Composites Based on Few-Layer Graphene and CNTs.

Project description:In this paper, we report a cost-effective and scalable approach to produce highly homogeneous graphene and CNT-based silicone composites with potential applications in diverse fields of research, including biosensors and wearable electronics. This approach includes the fabrication of hybrid fillers based on few-layer graphene and CNTs by water solution blending and manufacturing of graphene/CNT/PDMS composites through calendering in a three-roll mill. The influence of processing parameters, the graphene/CNT ratio, and hybrid filler loading was thoroughly investigated, and the optimal parameters for producing hybrid composites with superior electrical and mechanical properties were found. It was also confirmed that the graphene/CNT hybrid system exhibits a synergistic effect of non-covalent interactions between graphene sheets and CNT sidewalls. This synergistic effect prevents the aggregation of graphene sheets, facilitates the dispersion of graphene and CNTs in the silicone matrix, and contributes to the superior properties of hybrid composites compared to composites with either of these fillers alone.

| S-EPMC8145146 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data