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Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3].


ABSTRACT: We present the synthesis and characterization of the first non-classical Cl(i) polyinterhalide [NMe4][F(ClF)3] as well as the homologous polychloride [NPr3Me][Cl7]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl2, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)3]- anion.

SUBMITTER: Prohm P 

PROVIDER: S-EPMC8117328 | biostudies-literature |

REPOSITORIES: biostudies-literature

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