Unknown

Dataset Information

0

Heteroleptic LaIII Anilate/Dicarboxylate Based Neutral 3D-Coordination Polymers.


ABSTRACT: Three new 3D metal-organic frameworks of lanthanum based on mixed anionic ligands, [(La2(pQ)2(BDC)4)·4DMF]n, [(La2(pQ)2(DHBDC)4)·4DMF]n, [(La2(CA)2(BDC)4)·4DMF]n (pQ-dianion of 2,5-dihydroxy-3,6-di-tert-butyl-para-quinone, CA-dianion of chloranilic acid, BDC-1,4-benzenedicarboxylate, DHBDC-2,5-dihydroxy-1,4-benzenedicarboxylate and DMF-N,N'-dimethylformamide), were synthesized using solvothermal methodology. Coordination polymers demonstrate the rare xah or 4,6T187 topology of a 3D framework. The homoleptic 2D-coordination polymer [(La2(pQ)3)·4DMF]n was obtained as a by-product in the course of synthetic procedure optimization. The thermal stability, spectral characteristics and porosity of coordination polymers were investigated.

SUBMITTER: Trofimova OY 

PROVIDER: S-EPMC8123117 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC10489008 | biostudies-literature
| S-EPMC6644930 | biostudies-literature
| S-EPMC5888180 | biostudies-literature
| S-EPMC4309420 | biostudies-literature
| S-EPMC6572630 | biostudies-literature
| S-EPMC10535540 | biostudies-literature
| S-EPMC8998537 | biostudies-literature
| S-EPMC7000376 | biostudies-literature
| S-EPMC7345804 | biostudies-literature
| S-EPMC6415121 | biostudies-literature