Selective catalytic transformation of lignin with guaiacol as the only liquid product.

ABSTRACT: Guaiacol is an important feedstock for producing various high-value chemicals. However, the current production route of guaiacol relies heavily on fossil resources. Using lignin as a cheap and renewable feedstock to selectively produce guaiacol has great potential, but it is a challenge because of its heterogeneity and inert reactivity. Herein, we discovered that La(OTf)₃ could catalyze the transformation of lignin with guaiacol as the only liquid product. In the reaction, La(OTf)₃ catalyzed the hydrolysis of lignin ether linkages to form alkyl-syringol and alkyl-guaiacol, which further underwent decarbonization and demethoxylation to produce guaiacol with a yield of up to 25.5 wt%, and the remaining residue was solid. In the scale-up experiment, the isolated yield of guaiacol reached up to 21.2 wt%. To our knowledge, this is the first work to produce pure guaiacol selectively from lignin. The bio-guaiacol may be considered as a platform to promote lignin utilization.

SUBMITTER: Shen X 

PROVIDER: S-EPMC8148073 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature