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ABSTRACT:
SUBMITTER: Cao J
PROVIDER: S-EPMC8152619 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Cao Jing J Ma Wenjie W Lyu Kangjie K Zhuang Lin L Cong Hengjiang H Deng Hexiang H
Chemical science 20200319 15
We report the design and synthesis of a titanium catecholate framework, MOF-217, comprised of 2,4,6-tri(3,4-dihydroxyphenyl)-1,3,5-triazine (TDHT) and isolated TiO<sub>6</sub> clusters, with 2-fold interpenetrated <b>srs</b> topology. The dynamics of the organic linker, breaking the <i>C</i> <sub>3h</sub> symmetry, allowed for reversible twist and sliding between interpenetrated frames upon temperature change and the inclusion of small molecules. Introduction of 28 wt% imidazole into the pores o ...[more]