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Optically Transparent and Toughened Poly(methyl methacrylate) Composite Films with Acylated Cellulose Nanofibers.


ABSTRACT: In this work, nanocomposites of poly(methyl methacrylate) (PMMA) with cellulose nanofiber (CNF) were prepared by a solution casting technique. CNF was modified by propionic anhydride (PA) to form surface-propionylated CNF (CNFp) to improve its compatibility with the PMMA matrix. CNF, CNFp, and acetylated CNF were compared with respect to their influence as fillers in PMMA composite films by ultraviolet-visible transmittance, haze values, tensile strength testing, and water contact angle measurement. It was demonstrated that 1 wt % of CNFp has good compatibility and uniform dispersion in the PMMA matrix, as demonstrated by the formation of a smooth surface composite film with good transparency, enhanced tensile properties, improved toughness, and lower wettability. Therefore, PMMA/CNFp composite films have great potential for use in several applications such as lightweight transparent materials, window substitutes, and see-through packaging.

SUBMITTER: Jamaluddin N 

PROVIDER: S-EPMC8153788 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Optically Transparent and Toughened Poly(methyl methacrylate) Composite Films with Acylated Cellulose Nanofibers.

Jamaluddin Naharullah N   Hsu Yu-I YI   Asoh Taka-Aki TA   Uyama Hiroshi H  

ACS omega 20210413 16


In this work, nanocomposites of poly(methyl methacrylate) (PMMA) with cellulose nanofiber (CNF) were prepared by a solution casting technique. CNF was modified by propionic anhydride (PA) to form surface-propionylated CNF (CNFp) to improve its compatibility with the PMMA matrix. CNF, CNFp, and acetylated CNF were compared with respect to their influence as fillers in PMMA composite films by ultraviolet-visible transmittance, haze values, tensile strength testing, and water contact angle measurem  ...[more]

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