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Nanostructured Molybdenum Oxides from Aluminium-Based Intermetallic Compound: Synthesis and Application in Hydrogen Evolution Reaction.

ABSTRACT: Characterized by a large surface area to volume ratio, nanostructured metal oxides possess unique chemical and physical properties with applications in electronics, catalysis, sensors, etc. In this study, Mo₃Al₈, an intermetallic compound, has been used as a precursor to obtain nanostructured molybdenum oxides. It was prepared into ribbons by arc-melting and melt-spinning techniques. Single and double-step free corrosion of the as-quenched material have been studied in 1 M KOH, 1 M HF and 1.25 M FeCl₃ at room temperature. In both cases, nanostructured molybdenum oxides were obtained on a surface layer a few microns thick. Two of the as-prepared samples were tested for their electrocatalytic capability for hydrogen evolution reaction (HER) in 0.5 M H₂SO₄ giving low onset potential (-50 mV, -45 mV), small Tafel slopes (92 mV dec^-1, 9 mV dec^-1) and high exchange current densities (0.08 mA cm^-2, 0.35 mA cm^-2 respectively). The proposed nanostructured molybdenum oxides are cost-effective and sustainable due to the cheap and abundant starting material used and the simple synthetic route, paving the way for their possible application as HER electrocatalysts.

SUBMITTER: Raj D

PROVIDER: S-EPMC8156916 | biostudies-literature |

REPOSITORIES: biostudies-literature

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