Ontology highlight
ABSTRACT:
SUBMITTER: Machalska E
PROVIDER: S-EPMC8179112 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Machalska Ewa E Zajac Grzegorz G Baranska Malgorzata M Kaczorek Dorota D Kawęcki Robert R Lipiński Piotr F J PFJ Rode Joanna E JE Dobrowolski Jan Cz JC
Chemical science 20201102 3
Raman optical activity (ROA) spectra recorded for a chiral naphthalene diimide derivative (nBu-NDI-BINAM) dissolved in a series of solvents exhibit strong solute to solvent induced chirality with: (1) dominating bands of solvents, (2) <i>n</i>Bu-NDI-BINAM resonance ROA (RROA) bands which are barely visible, (3) monosignate RROA Solvent spectra with an unexpected sign concordant with that of the ECD band of the resonant electronic state, (4) bisignate RROA bands for a few solvents, and (5) superp ...[more]