Ontology highlight
ABSTRACT:
SUBMITTER: Rios P
PROVIDER: S-EPMC8179255 | biostudies-literature | 2020 Nov
REPOSITORIES: biostudies-literature
Ríos Pablo P Martín-de la Calle Rocío R Vidossich Pietro P Fernández-de-Córdova Francisco José FJ Lledós Agustí A Conejero Salvador S
Chemical science 20201110 5
A reversible carbon-boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(I <sup><i>t</i></sup> Bu<sup>i</sup>Pr')(I <sup><i>t</i></sup> Bu<sup>i</sup>Pr)][BAr<sup>F</sup>], <b>1</b>, with tricoordinated boranes HBR<sub>2</sub>. X-ray diffraction studies provided structural snapshots of the sequence of reactions involved in the process. At low temperature, we observed the initial formation of the unprecedented σ-BH complexes ...[more]