Strategies for the Removal of Polysaccharides from Biorefinery Lignins: Process Optimization and Techno Economic Evaluation.
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ABSTRACT:
SUBMITTER: Corderi S
PROVIDER: S-EPMC8197879 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:While exports from the meat industry in New Zealand constitute a valuable source of foreign exchange, the meat industry is also responsible for the generation of large masses of waste streams. These meat processing waste streams are largely biologically unstable and are capable of leading to unfavourable environmental outcomes if not properly managed. To enable the effective management of the meat processing waste streams, a value-recovery based strategy, for the complete valorisation of the meat processing waste biomass, is proposed. In the present study therefore, a biorefinery system that integrates the biomass conversion technologies of hydrolysis, esterification, anaerobic digestion and hydrothermal liquefaction has been modelled, simulated and optimized for enhanced environmental performance and economic performance. It was determined that an initial positive correlation between the mass feed rate of the waste to the biorefinery system and its environmental performance exists. However, beyond an optimal total mass feed rate of the waste stream there is a deterioration of the environmental performance of the biorefinery system. It was also determined that economies of scale ensure that any improvement in the economic performance of the biorefinery system with increasing total mass feed rate of the waste stream, is sustained. The present study established that the optimized meat waste biorefinery system facilitated a reduction in the unit production costs of the value-added products of biodiesel, biochar and biocrude compared the literature-obtained unit production costs of the respective aforementioned products when generated from stand-alone systems. The unit production cost of biogas was however shown to be comparable to the literature-obtained unit production cost of biogas. Finally, the present study showed that the optimized meat processing waste biorefinery could achieve enhanced economic performance while simultaneously maintaining favourable environmental sustainability.
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Project description:BackgroundThe overall goal of the present study is to investigate the economics of an integrated biorefinery converting hybrid poplar into jet fuel, xylitol, and formic acid. The process employs a combination of integrated biological, thermochemical, and electrochemical conversion pathways to convert the carbohydrates in poplar into jet fuel, xylitol, and formic acid production. The C5-sugars are converted into xylitol via hydrogenation. The C6-sugars are converted into jet fuel via fermentation into ethanol, followed by dehydration, oligomerization, and hydrogenation into jet fuel. CO2 produced during fermentation is converted into formic acid via electrolysis, thus, avoiding emissions and improving the process's overall carbon conversion.ResultsThree different biorefinery scales are considered: small, intermediate, and large, assuming feedstock supplies of 150, 250, and 760 dry ktonne of poplar/year, respectively. For the intermediate-scale biorefinery, a minimum jet fuel selling price of $3.13/gallon was obtained at a discount rate of 15%. In a favorable scenario where the xylitol price is 25% higher than its current market value, a jet fuel selling price of $0.64/gallon was obtained. Co-locating the biorefinery with a power plant reduces the jet fuel selling price from $3.13 to $1.03 per gallon.ConclusionA unique integrated biorefinery to produce jet fuel was successfully modeled. Analysis of the biorefinery scales shows that the minimum jet fuel selling price for profitability decreases with increasing biorefinery scale, and for all scales, the biorefinery presents favorable economics, leading to a minimum jet fuel selling price lower than the current price for sustainable aviation fuel (SAF). The amount of xylitol and formic produced in a large-scale facility corresponds to 43% and 25%, respectively, of the global market volume of these products. These volumes will saturate the markets, making them infeasible scenarios. In contrast, the small and intermediate-scale biorefineries have product volumes that would not saturate current markets, does not present a feedstock availability problem, and produce jet fuel at a favorable price given the current SAF policy support. It is shown that the price of co-products greatly influences the minimum selling price of jet fuel, and co-location can further reduce the price of jet fuel.
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Project description:In this work we have analyzed the pine and spruce softwood lignin fraction recovered from a novel pressurized hot water extraction pilot process. The lignin structure was characterized using multiple NMR techniques and the thermal properties were analyzed using thermal gravimetric analysis. Acetylated and selectively methylated derivatives were prepared, and their structure and properties were analyzed and compared to the unmodified lignin. The lignin had relatively high molar weight and low PDI values and even less polydisperse fractions could be obtained by fractionation based on solubility in i-PrOH. Condensation, especially at the 5-position, was detected in this sulphur-free technical lignin, which had been enriched with carbon compared to the milled wood lignin (MWL) sample of the same wood chips. An increase in phenolic and carboxylic groups was also detected, which makes the lignin accessible to chemical modification. The lignin was determined to be thermally stable up to (273⁻302 °C) based on its Tdst 95% value. Due to the thermal stability, low polydispersity, and possibility to tailor its chemical properties by modification of its hydroxyl groups, possible application areas for the lignin could be in polymeric blends, composites or in resins.
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