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Highly Sensitive and Selective Fluorescence "Turn-On" Detection of Pb (II) Based on Fe₃O₄@Au-FITC Nanocomposite.

ABSTRACT: New nanocomposites, Fe₃O₄@Au-FITC, were prepared and explored to develop a fluorescent detection of Pb²⁺. The Fe₃O₄@AuNPs-FITC nanocomposites could be etched by Pb²⁺ in the presence of Na₂S₂O₃, leading to fluorescence recovery of FITC quenched by Fe₃O₄@Au nanocomposites. With the increase of Pb²⁺ concentration, the fluorescence recovery of Fe₃O₄@AuNPs-FITC increased gradually. Under optimized conditions, a detection limit of 5.2 nmol/L of Pb²⁺ with a linear range of 0.02-2.0 µmol/L were obtained. The assay demonstrated negligible response to common metal ions. Recoveries of 98.2-106.4% were obtained when this fluorescent method was applied in detecting Pb²⁺ spiked in a lake-water sample. The above results demonstrated the high potential of ion-induced nanomaterial etching in developing robust fluorescent assays.

SUBMITTER: Cai Y

PROVIDER: S-EPMC8198146 | biostudies-literature |

REPOSITORIES: biostudies-literature

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