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Ultrasound-boosted selectivity of CO in CO₂ electrochemical reduction.

ABSTRACT: Among the possible products of CO₂ electrochemical reduction, CO plays a unique and vital role, which can be an ideal feedstock for further reduction to C₂₊ products, and also the important component of syngas that can be used as feedstock for value-added chemicals and fuels. However, it is still a challenge to tune the CO selectivity on Cu electrode. Here we newly construct an ultrasound-assisted electrochemical method for CO₂ reduction, which can tune the selectivity of CO₂ to CO from less than 10% to >80% at -1.18 V versus (vs.) reversible hydrogen electrode (RHE). The partial current density of CO production is significantly improved by 15 times. By in-situ Raman study, the dominating factor for the improved CO production is attributed to the accelerated desorption of *CO intermediate. This work provides a facile method to tune the product selectivity in CO₂ electrochemical reduction.

SUBMITTER: Yang Y

PROVIDER: S-EPMC8213958 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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Ultrasound-boosted selectivity of CO in CO2 electrochemical reduction.

Yang Yang Y Feng Yiqing Y Li Kejian K Ajmal Saira S Cheng Hanyun H Gong Kedong K Zhang Liwu L

Ultrasonics sonochemistry 20210608

Among the possible products of CO2 electrochemical reduction, CO plays a unique and vital role, which can be an ideal feedstock for further reduction to C2+ products, and also the important component of syngas that can be used as feedstock for value-added chemicals and fuels. However, it is still a challenge to tune the CO selectivity on Cu electrode. Here we newly construct an ultrasound-assisted electrochemical method for CO2 reduction, which can tune the selec ...[more]

PMID: 34134069

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