Unknown

Dataset Information

0

Electronic Characterization of a Charge-Transfer Complex Monolayer on Graphene.


ABSTRACT: Organic charge-transfer complexes (CTCs) formed by strong electron acceptor and strong electron donor molecules are known to exhibit exotic effects such as superconductivity and charge density waves. We present a low-temperature scanning tunneling microscopy and spectroscopy (LT-STM/STS) study of a two-dimensional (2D) monolayer CTC of tetrathiafulvalene (TTF) and fluorinated tetracyanoquinodimethane (F4TCNQ), self-assembled on the surface of oxygen-intercalated epitaxial graphene on Ir(111) (G/O/Ir(111)). We confirm the formation of the charge-transfer complex by dI/dV spectroscopy and direct imaging of the singly occupied molecular orbitals. High-resolution spectroscopy reveals a gap at zero bias, suggesting the formation of a correlated ground state at low temperatures. These results point to the possibility to realize and study correlated ground states in charge-transfer complex monolayers on weakly interacting surfaces.

SUBMITTER: Kumar A 

PROVIDER: S-EPMC8223480 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC4585939 | biostudies-literature
| S-EPMC3950808 | biostudies-other
| S-EPMC5572701 | biostudies-literature
| S-EPMC4673461 | biostudies-literature
| S-EPMC5344567 | biostudies-literature
| S-EPMC7080519 | biostudies-literature
| S-EPMC2764459 | biostudies-literature
| S-EPMC4490386 | biostudies-literature
| S-EPMC5788010 | biostudies-literature
| S-EPMC4855231 | biostudies-literature