Dataset Information

High electrochemical and mechanical performance of zinc conducting-based gel polymer electrolytes.

ABSTRACT: Zinc ionic conducting-based gel polymer electrolytes (GPEs) were fabricated from carboxymethyl cellulose (CMC) and three different zinc salts in a mass ratio ranging within 0-30 wt%. The effects of zinc salt and loading level on the structure, thermal, mechanical, mechanical stability, and morphological properties, as well as electrochemical properties of the GPEs films, were symmetrically investigated. The mechanical properties and mechanical stability of CMC were improved with the addition of zinc acetate, zinc sulphate, and zinc triflate, approaching the minimum requirement of a solid state membrane for battery. The maximum ionic conductivity of 2.10 mS cm^-1 was achieved with the addition of 15 wt% zinc acetate (ZnA), GPE_A15. The supported parameters, indicating the presence of the amorphous region that likely supported Zn²⁺ movement in the CMC chains, were clearly revealed with the increase in the number of mobile Zn²⁺ carriers in FT-IR spectra and the magnitude of ionic transference number, the decrease of the enthalpy of fusion in DSC thermogram, and the shifting to lower intensity of 2θ in XRD pattern. The developed CMC/ZnA complex-based GPEs are very promising for their high ionic conductivity as well as good mechanical properties and the ability for long-term utilization in a zinc ion battery.

SUBMITTER: Dueramae I

PROVIDER: S-EPMC8225769 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:Flexible electrochemical supercapacitors (FESCs) are emerging as innovative energy storage systems, characterized by their stable performance, long cycle life, and portability/foldability. Crucial components of FESCs, such as electrodes and efficient electrolytes, have become the focus of extensive research. Herein, we examine deep eutectic solvent (DES)-based polymer gel systems for their cost-effective accessibility, simple synthesis, excellent biocompatibility, and exceptional thermal and electrochemical stability. We used a mixture a DES, LiClO4-2-Oxazolidinone as the electroactive species, and a polymer, either polyvinyl alcohol (PVA) or polyacrylamide (PAAM) as a redox additive/plasticizer. This combination facilitates a unique ion-transport process, enhancing the overall electrochemical performance of the polymer gel electrolyte. We manufactured and used LiClO4-2-Oxazolidinone (LO), polyvinyl alcohol-LiClO4-2-Oxazolidinone (PVA-LO), and polyacrylamide-LiClO4-2-Oxazolidinone (PAAM-LO) electrolytes to synthesize an MnO2 symmetric FESC. To evaluate their performance, we analyzed the MnO2 symmetric FESC using various electrolytes with cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The FESC featuring the PVA-LO electrolyte demonstrated superior electrochemical and mechanical performances. This solid-state MnO2 symmetric FESC exhibited a specific capacitance of 121.6 F/g within a potential window of 2.4 V. Due to the excellent ionic conductivity and the wide electrochemical operating voltage range of the PVA-LO electrolyte, a high energy density of 97.3 Wh/kg at 1200 W/kg, and a long-lasting energy storage system (89.7% capacitance retention after 5000 cycles of GCD at 2 A/g) are feasibly achieved. For practical applications, we employed the MnO2 symmetric FESCs with the PVA-LO electrolyte to power a digital watch and a light-emitting diode, further demonstrating their real-world utility.

Dataset Information

High electrochemical and mechanical performance of zinc conducting-based gel polymer electrolytes.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets