An Analysis of the Effect of ZIF-8 Addition on the Separation Properties of Polysulfone at Various Temperatures.
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ABSTRACT:
SUBMITTER: Papchenko K
PROVIDER: S-EPMC8229596 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:In this study, we prepared and characterized composite films formed by amorphous poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and particles of the size-selective Zeolitic Imidazolate Framework 8 (ZIF-8). The aim was to increase the permselectivity properties of pure PPO using readily available materials to enable the possibility to scale-up the technology developed in this work. The preparation protocol established allowed robust membranes with filler loadings as high as 45 wt% to be obtained. The thermal, morphological, and structural properties of the membranes were analyzed via DSC, SEM, TGA, and densitometry. The gas permeability and diffusivity of He, CO2, CH4, and N2 were measured at 35, 50, and 65 °C. The inclusion of ZIF-8 led to a remarkable increase of the gas permeability for all gases, and to a significant decrease of the activation energy of diffusion and permeation. The permeability increased up to +800% at 45 wt% of filler, reaching values of 621 Barrer for He and 449 for CO2 at 35 °C. The ideal size selectivity of the PPO membrane also increased, albeit to a lower extent, and the maximum was reached at a filler loading of 35 wt% (1.5 for He/CO2, 18 for CO2/N2, 17 for CO2/CH4, 27 for He/N2, and 24 for He/CH4). The density of the composite materials followed an additive behavior based on the pure values of PPO and ZIF-8, which indicates good adhesion between the two phases. The permeability and He/CO2 selectivity increased with temperature, which indicates that applications at higher temperatures than those inspected should be encouraged.
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Project description:Metal-organic frameworks (MOFs) are found to be promising porous crystalline materials for application in gas separation. Considering that mixed matrix membranes usually increase the gas separation performance of a polymer by increasing selectivity, permeability, or both (i.e., perm-selectivity), the zeolitic imidazole framework-95 (ZIF-95) MOF was dispersed for the first time in polysulfone (PSF) polymer to form mixed matrix membranes (MMMs), namely, ZIF-95/PSF. The fabricated ZIF-95/PSF membranes were examined for the separation of various gases. The characterization of solvothermally synthesized ZIF-95 was carried out using different analyses such as powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), porosity measurements, etc. ZIF-95 was mixed with PSF at 8%, 16%, 24%, and 32% weight percent to form different loading MMMs. SEM analysis of membranes revealed good compatibility/adhesion between the MOF and polymer. The permeability of He, H2, O2, CO2, N2, and CH4 were measured for the pure and composite membranes. The ideal selectivity of different gas pairs were calculated and compared with reported mixed matrix membranes. The maximum increases in permeabilities were observed in 32% loaded membrane; nevertheless, these performance/permeability increases were at the expense of a slight decrease of selectivity. In the optimally loaded membrane (i.e., 24 wt% loaded membrane), the permeability of H2, O2, and CO2 increased by 80.2%, 78.0%, and 67.2%, respectively, as compared to the pure membrane. Moreover, the selectivity of H2/CH4, O2/N2, and H2/CO2 gas pairs also increased by 16%, 15%, and 8% in the 24% loaded membrane, respectively.
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Project description:Polysulfone membranes exhibit resistance to high temperature with low manufacturing cost and high efficiency in the separation process. The composition of gases is an important step that estimates the efficiency of separation in membranes. As membrane types are currently becoming in demand for CO2/CH4 segregation, polysulfone will be an advantageous alternative to have in further studies. Therefore, research is undertaken in this study to evaluate two solvents: chloroform (CF) and tetrahydrofuran (THF). These solvents are tested for casting polymeric membranes from polysulfone (PSF) to separate every single component from a binary gas mixture of CO2/CH4. In addition, the effect of gas pressure was conducted from 1 to 10 bar on the behavior of the permeability and selectivity. The results refer to the fact that the maximum permeability of CO2 and CH4 for THF is 62.32 and 2.06 barrer at 1 and 2 bars, respectively. Further, the maximum permeability of CF is 57.59 and 2.12 barrer at 1 and 2 bars, respectively. The outcome selectivity values are 48 and 36 for THF and CF at 1 bar, accordingly. Furthermore, the study declares that with the increase in pressure, the permeability and selectivity values drop for CF and THF. The performance for polysulfone (PSF) membrane that is manufactured with THF is superior to that of CF relative to the Robeson upper bound. Therefore, through the results, it can be deduced that the solvent during in-situ synthesis has a significant influence on the gas separation of a binary mixture of CO2/CH4.
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Project description:Currently, finding high capacity adsorbents with large selectivity to capture Xe is still a great challenge. In this work, nitrogen-doped porous carbons were prepared by programmable temperature carbonization of zeolitic imidazolate framework-8 (ZIF-8) and ZIF-8/xylitol composite precursors and the resultant samples are marked as Carbon-Z and Carbon-ZX, respectively. Further adsorption measurements indicate that ZIF-derived nitrogen-doped Carbon-ZX exhibits extremely high Xe capacity of 4.42 mmol g(-1) at 298 K and 1 bar, which is higher than almost all other pristine MOFs such as CuBTC, Ni/DOBDC, MOF-5 and Al-MIL-53, and even more than three times of the matrix ZIF-8 at similar conditions. Moreover, Carbon-ZX also shows the highest Xe/N2 selectivity about ~120, which is much larger than all other reported MOFs. These remarkable features illustrate that ZIF-derived nitrogen-doped porous carbon is an excellent adsorbent for Xe adsorption and separation at room temperature.
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Project description:Metal-organic framework (MOF) membranes show great potential in the separation of acetylene mixtures. In this work, we have prepared ZIF-8 membranes on polyamide (PA) substrates for the highly selective separation of acetylene/methane and acetylene/carbon dioxide mixtures. The C2H2/CH4 and C2H2/CO2 mixtures can be successfully separated using the ZIF-8 membranes, with separation factors of 12.1 and 1.8, respectively. Based on the results of the cross-permeation tests of C2H2/CH4, CO2/CH4, and C2H2/CO2, the separation mechanism of C2H2/CH4 in our ZIF-8 membrane can be attributed to a higher affinity for acetylene and molecular sieving effect, while C2H2/CO2 separation is related to thermodynamic factors. It is worth noting that this is the first example of MOF membranes to successfully separate C2H2 from CH4 and CO2.
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