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Electropolymerized Poly(3,4-ethylenedioxythiophene)/Screen-Printed Reduced Graphene Oxide-Chitosan Bilayer Electrodes for Flexible Supercapacitors.

ABSTRACT: An electropolymerized poly(3,4-ethylenedioxythiophene) (PEDOT)/screen-printed reduced graphene oxide (rGO)-chitosan (CS) bilayer material was coated on carbon cloth to form electrodes for gel-electrolyte flexible supercapacitors. The conductive polymer and carbon-based materials mainly contribute pseudocapacitance (PC) and electrical double-layer capacitance (EDLC), respectively. The high porosity and hydrophilicity of the PEDOT/rGO-CS bilayer material offers a large contact area and improves the contact quality for the gel electrolyte, thereby enhancing the capacitive performance. Cyclic voltammetry (CV) under a potential scan rate of 2 mV/s revealed that a maximum areal capacitance of 1073.67 mF/cm² was achieved. The capacitance contribution ratio PC/EDLC was evaluated to be ∼67/33 by the Trasatti method. A 10,000-cycle CV test showed a capacitance retention rate of 99.3% under a potential scan rate of 200 mV/s, indicating good stability. The areal capacitance remains similar under bending with a bending curvature of up to 1.5 cm^-1.

SUBMITTER: Tseng CH

PROVIDER: S-EPMC8246451 | biostudies-literature |

REPOSITORIES: biostudies-literature

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