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ABSTRACT:
SUBMITTER: Crumbach M
PROVIDER: S-EPMC8252115 | biostudies-literature | 2021 Apr
REPOSITORIES: biostudies-literature
Crumbach Merian M Bachmann Jonas J Fritze Lars L Helbig Andreas A Krummenacher Ivo I Braunschweig Holger H Helten Holger H
Angewandte Chemie (International ed. in English) 20210317 17
Access to dithiophene-fused oxadiborepins and the first azadiborepins attained via a modular synthesis route are presented. The new compounds emit intense blue light, some of which demonstrate fluorescence quantum yields close to unity. Cyclic voltammetry (CV) revealed electrochemically reversible one-electron reduction processes. The weak aromatic character of the novel 1,2,7-azadiborepin ring is demonstrated with in-depth theoretical investigations using nucleus-independent chemical shift (NIC ...[more]