Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.
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ABSTRACT: Rhodium-electrocatalyzed arene C-H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C-H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C-H activation by a bimetallic rhodium catalysis manifold.
SUBMITTER: Tan X
PROVIDER: S-EPMC8252749 | biostudies-literature |
REPOSITORIES: biostudies-literature
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