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Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.


ABSTRACT: Rhodium-electrocatalyzed arene C-H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C-H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C-H activation by a bimetallic rhodium catalysis manifold.

SUBMITTER: Tan X 

PROVIDER: S-EPMC8252749 | biostudies-literature |

REPOSITORIES: biostudies-literature

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