Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tunable Hydrophobicity via Dimensionally Confined Polymerization of Organometallic Adducts.

ABSTRACT: Fabrication of tunable fine textures on solid metal surfaces often demands sophisticated reaction/processing systems. By exploiting in situ polymerization and self-assembly of inorganic adducts derived from liquid metals (the so-called HetMet reaction) with concomitant solidification, solid metal films with tunable texture are readily fabricated. Serving as a natural dimensional confinement, interparticle pores and capillary-adhered thin liquid films in a pre-packed bed of undercooled liquid metal particles lead to the expeditious surface accumulation of organometallic synthons, which readily oligomerize and self-assemble into concentration-dictated morphologies/patterns. Tuning particle size, particle packing (flat or textured), and reactant concentration generates diverse, autonomously organized organometallic structures on a metal particle bed. Concomitant solidification and sintering of the underlying undercooled particle bed led to a multiscale patterned solid metal surface. The process is illustrated by creating tunable features on pre-organized metal particle beds with concomitant tunable wettability as illustrated through the so-called petal and lotus effects.

SUBMITTER: Chang JJ

PROVIDER: S-EPMC8252771 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Effects of the Substrate on Interfacial Polymerization: Tuning the Hydrophobicity via Polyelectrolyte Deposition.

Project description:Interfacial polymerization (IP) has been the key method for the fabrication of the thin film composite (TFC) membranes that are extensively employed in reverse osmosis (RO) and forward osmosis (FO). However, the role of the substrate surface hydrophilicity in the formation of the IP-film remains a controversial issue to be further addressed. This study characterized the IP films formed on a series of polyacrylonitrile (PAN) substrates whose hydrophilicities (from ~38 to ~93 degrees) were varied via different approaches, including the alkaline treatment and the deposition of various polycations. It was revealed that delamination could occur when the IP film was formed on a relatively hydrophilic surface; the integrity of the TFC membranes was substantially improved, owing to the modification of the polyelectrolyte deposition. On the other hand, the characterization indicated that the TFC membrane could have an enhanced efficiency (with a factor of ~2) when the substrate was relatively hydrophilic. It was established that the polyelectrolyte deposition could be exploited to effectively tune the substrate surface hydrophobicity, thereby providing more degrees of freedom for the optimization of the TFC membranes fabrication.

| S-EPMC7599731 | biostudies-literature

Oxidation kinetics and non-Marcusian charge transfer in dimensionally confined semiconductors.

Project description:Electrochemical reactions represent essential processes in fundamental chemistry that foster a wide range of applications. Although most electrochemical reactions in bulk substances can be well described by the classical Marcus-Gerischer charge transfer theory, the realistic reaction character and mechanism in dimensionally confined systems remain unknown. Here, we report the multiparametric survey on the kinetics of lateral photooxidation in structurally identical WS2 and MoS2 monolayers, where electrochemical oxidation occurs at the atomically thin monolayer edges. The oxidation rate is correlated quantitatively with various crystallographic and environmental parameters, including the density of reactive sites, humidity, temperature, and illumination fluence. In particular, we observe distinctive reaction barriers of 1.4 and 0.9 eV for the two structurally identical semiconductors and uncover an unusual non-Marcusian charge transfer mechanism in these dimensionally confined monolayers due to the limit in reactant supplies. A scenario of band bending is proposed to explain the discrepancy in reaction barriers. These results add important knowledge into the fundamental electrochemical reaction theory in low-dimensional systems.

| S-EPMC10333350 | biostudies-literature

Tunable High Entropy Lanthanide Oxide Microspheres via Confined Electroprecipitation in Emulsion Droplet Scaffolds.

Project description:Emergent high entropy nanomaterials and their associated complex surface structure hold promise to unlock unique catalytic intermediate pathways and photonic/plasmonic interactions; however, synthetic strategies to tune the size, morphological, and stoichiometric properties remain limited. This work demonstrates a confined electro-precipitation mechanism for the formation of tunable, high-entropy oxide microspheres within emulsion droplet scaffolds. This mechanism complements a traditional confined electrodeposition mechanism and explains the previously observed anomalous formation of thermodynamically unfavorable particles, including lanthanide species. Mass transfer studies reveal that microsphere coverage over a surface may be tuned and modeled by using a time-dependent modified Levich equation. Additionally, morphological tuning was demonstrated as a function of experimental conditions, such as rotation rate and precursor concentration. Finally, extension to multimetallic species permitted the generation of high-entropy lanthanide oxide microspheres, which were confirmed to have equimolar stoichiometries via energy dispersive spectroscopy and inductively coupled plasma mass spectrometry. This novel method promises to generate tunable, complex oxides with applications to thermal catalysis, optics, and applications yet unknown.

| S-EPMC10941274 | biostudies-literature

Video data of hydraulic fracture propagation in two-dimensionally confined gelatin plates.

Project description:This data article presents 36 raw and unprocessed video files which were obtained during hydraulic fracture experiments in two-dimensionally confined gelatin plates. Initiation and propagation of bi-wing fractures were recorded at 50 frames per second with the resolution of 1920 × 1080 pixels. The gelatin stiffness, the fluid viscosity, and the flow rate were controlled. With these data, the fracture geometry, such as length, width, and propagation velocity were discussed in the research article "Characteristics of steady-state propagation of hydraulic fractures in ductile elastic and two-dimensionally confined plate media" Ham and Kwon et al., 2019.

| S-EPMC6600779 | biostudies-literature

Nanocompartment-confined polymerization in living systems.

Project description:Polymerization in living systems has become an effective strategy to regulate cell functions and behavior. However, the requirement of high concentrations of monomers, the existence of complicated intracorporal interferences, and the demand for extra external stimulations hinder their further biological applications. Herein, a nanocompartment-confined strategy that provides a confined and secluded environment for monomer enrichment and isolation is developed to achieve high polymerization efficiency, reduce the interference from external environment, and realize broad-spectrum polymerizations in living systems. For exogenous photopolymerization, the light-mediated free-radical polymerization of sodium 4-styrenesulfonate induces a 2.7-fold increase in the reaction rate with the protection of a confined environment. For endogenous hydrogen peroxide-responsive polymerization, p‑aminodiphenylamine hydrochloride embedded in a nanocompartment not only performs a 6.4-fold higher reaction rate than that of free monomers, but also activates an effective second near-infrared photoacoustic imaging-guided photothermal immunotherapy at tumor sites. This nanocompartment-confined strategy breaks the shackles of conventional polymerization, providing a universal platform for in vivo synthesis of polymers with diverse structures and functions.

| S-EPMC10460442 | biostudies-literature

Fabrication of corona-free nanoparticles with tunable hydrophobicity.

Project description:A protein corona is formed at the surface of nanoparticles in the presence of biological fluids, masking the surface properties of the particle and complicating the relationship between chemical functionality and biological effects. We present here a series of zwitterionic NPs of variable hydrophobicity that do not adsorb proteins at moderate levels of serum protein and do not form hard coronas at physiological serum concentrations. These particles provide platforms to evaluate nanobiological behavior such as cell uptake and hemolysis dictated directly by chemical motifs at the nanoparticle surface.

| S-EPMC4215884 | biostudies-literature

Preparation of Gold Nanocomposites with Tunable Charge and Hydrophobicity via the Application of Polymer/Surfactant Complexation.

Project description:During the synthesis of gold nanoparticle (NP) assemblies, the interfacial charge and hydrophobicity of the primary particles play a distinguished role. In the present article, we demonstrate that the association of poly(ethyleneimine) (PEI) capped gold NPs with sodium alkyl sulfates provide a powerful route for the manipulation of these interfacial properties. Dynamic light-scattering, electrophoretic mobility, UV-vis-near-infrared spectroscopy, nanoparticle tracking analysis, and transmission electron microscopy measurements were used to characterize the PEI/surfactant/gold nanoassemblies. The results indicate the formation of gold NPs surrounded by a PEI/surfactant shell with composition-dependent charge and hydrophobicity. The mean size and the aggregation of the nanoassemblies can be fine tuned by the amount of surfactant bound to the primary gold NPs as well as by the application of controlled mixing methods. The specific features of the prepared nanocomposites may be further exploited in next-generation applications.

| S-EPMC6645515 | biostudies-literature

Structurally Anisotropic Janus Particles with Tunable Amphiphilicity via Polymerization of Dynamic Complex Emulsions.

Project description:A facile one-step approach for the synthesis of physically and chemically anisotropic polymer particles with tunable size, shape, composition, wettability, and functionality is reported. Specifically, dynamically reconfigurable oil-in-water Janus emulsions containing photocurable hydrocarbon or fluorocarbon acrylate monomers as one of the droplet phases are used as structural templates to polymerize them into precision Janus particles with highly uniform anomalous morphologies including (hemi-) spheres, lenses, and bowls. During polymerization, each interface is exposed to a different chemical environment, yielding particles with an intrinsic Janus character that can be amplified via side-selective postfunctionalization. The fabrication method allows to start with various common emulsification techniques, thus generating particles in the range of 200 nm -150 μm, also at a technical scale. The anisotropic shape combined with the asymmetric wettability profile of the produced particles promotes their directed self-assembly into colloidal clusters as well as their directional alignment at fluid interfaces. We foresee the application of such Janus particles in technical emulsions or oil recovery, for the manufacturing of programmed self-assembled architectures, and for the engineering of microstructured interfaces.

| S-EPMC7842141 | biostudies-literature

Tunable backbone-degradable robust tissue adhesives via in situ radical ring-opening polymerization.

Project description:Adhesives with both robust adhesion and tunable degradability are clinically and ecologically vital, but their fabrication remains a formidable challenge. Here we propose an in situ radical ring-opening polymerization (rROP) strategy to design a backbone-degradable robust adhesive (BDRA) in physiological environment. The hydrophobic cyclic ketene acetal and hydrophilic acrylate monomer mixture of the BDRA precursor allows it to effectively wet and penetrate substrates, subsequently forming a deep covalently interpenetrating network with a degradable backbone via redox-initiated in situ rROP. The resulting BDRAs show good adhesion strength on diverse materials and tissues (e.g., wet bone >16 MPa, and porcine skin >150 kPa), higher than that of commercial cyanoacrylate superglue (~4 MPa and 56 kPa). Moreover, the BDRAs have enhanced tunable degradability, mechanical modulus (100 kPa-10 GPa) and setting time (seconds-hours), and have good biocompatibility in vitro and in vivo. This family of BDRAs expands the scope of medical adhesive applications and offers an easy and environmentally friendly approach for engineering.

| S-EPMC10539349 | biostudies-literature

Mesoporous Polymeric Ionic Liquid via Confined Polymerization for Laccase Immobilization towards Efficient Degradation of Phenolic Pollutants.

Project description:Laccase immobilization is a promising method that can be used for the recyclable treatment of refractory phenolic pollutants (e.g., chlorophenols) under mild conditions, but the method is still hindered by the trade-off limits of supports in terms of their high specific surface area and rich functional groups. Herein, confined polymerization was applied to create abundant amino-functionalized polymeric ionic liquids (PILs) featuring a highly specific surface area and mesoporous structure for chemically immobilizing laccase. Benefiting from this strategy, the specific surface area of the as-synthesized PILs was significantly increased by 60-fold, from 5 to 302 m2/g. Further, a maximum activity recovery of 82% towards laccase was recorded. The tolerance and circulation of the immobilized laccase under harsh operating conditions were significantly improved, and the immobilized laccase retained more than 84% of its initial activity after 15 days. After 10 cycles, the immobilized laccase was still able to maintain 80% of its activity. Compared with the free laccase, the immobilized laccase exhibited enhanced stability in the biodegradation of 2,4-dichlorophenol (2,4-DCP), recording around 80% (seven cycles) efficiency. It is proposed that the synergistic effect between PILs and laccase plays an important role in the enhancement of stability and activity in phenolic pollutant degradation. This work provides a strategy for the development of synthetic methods for PILs and the improvement of immobilized laccase stability.

| S-EPMC10059984 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data