Browse
Submit Data
Databases
API
Help

Dataset Information

20 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Construction of a Three-Dimensional BaTiO₃ Network for Enhanced Permittivity and Energy Storage of PVDF Composites.

ABSTRACT: Three-dimensional BaTiO₃ (3D BT)/polyvinylidene fluoride (PVDF) composite dielectrics were fabricated by inversely introducing PVDF solution into a continuous 3D BT network, which was simply constructed via the sol-gel method using a cleanroom wiper as a template. The effect of the 3D BT microstructure and content on the dielectric and energy storage properties of the composites were explored. The results showed that 3D BT with a well-connected continuous network and moderate grain sizes could be easily obtained by calcining a barium source containing a wiper template at 1100 °C for 3 h. The as-fabricated 3D BT/PVDF composites with 21.1 wt% content of 3D BT (3DBT-2) exhibited the best comprehensive dielectric and energy storage performances. An enhanced dielectric constant of 25.3 at 100 Hz, which was 2.8 times higher than that of pure PVDF and 1.4 times superior to the conventional nano-BT/PVDF 25 wt% system, was achieved in addition with a low dielectric loss of 0.057 and a moderate dielectric breakdown strength of 73.8 kV·mm^-1. In addition, the composite of 3DBT-2 exhibited the highest discharge energy density of 1.6 × 10^-3 J·cm^-3 under 3 kV·mm^-1, which was nearly 4.5 times higher than that of neat PVDF.

SUBMITTER: Bi X

PROVIDER: S-EPMC8269637 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Enhanced Energy Storage Performance of PVDF-Based Composites Using BN@PDA Sheets and Titania Nanosheets.

Project description:With the rapid development of modern electrical and electronic applications, the demand for high-performance film capacitors is becoming increasingly urgent. The energy density of a capacitor is dependent on permittivity and breakdown strength. However, the development of polymer-based composites with both high permittivity (εr) and breakdown strength (Eb) remains a huge challenge. In this work, a strategy of doping synergistic dual-fillers with complementary functionalities into polymer is demonstrated, by which high εr and Eb are obtained simultaneously. Small-sized titania nanosheets (STNSs) with high εr and high-insulating boron nitride sheets coated with polydopamine on the surface (BN@PDA) were introduced into poly(vinylidene fluoride) (PVDF) to prepare a ternary composite. Remarkably, a PVDF-based composite with 1 wt% BN@PDA and 0.5 wt% STNSs (1 wt% PVDF/BN@PDA-STNSs) shows an excellent energy storage performance, including a high εr of ~13.9 at 1 Hz, a superior Eb of ~440 kV/mm, and a high discharged energy density Ue of ~12.1 J/cm3. Moreover, the simulation results confirm that BN@PDA sheets improve breakdown strength and STNSs boost polarization, which is consistent with the experimental results. This contribution provides a new design paradigm for energy storage dielectrics.

| S-EPMC9267653 | biostudies-literature

Three-Dimensional PrGO-Based Sandwich Composites With MoS2 Flowers as Stuffings for Superior Lithium Storage.

Project description:Graphene-based MoS2 nanocomposites are expected to be promising anode materials for lithium ion batteries because of their large specific capacity and high conductivity. However, the aggregation of graphene and the weak interaction between the two components hinder their practical application. Inspired by the sandwich structure, novel three-dimensional flower-like MoS2-PrGO sandwich composites were proposed as an advanced anode material for lithium-ion batteries. The separated 2D ultrathin rGO nano-sheets were connected by PEO chains and assembled into a well-organized 3D layered spatial structure, which not only avoids the aggregation of graphene but also accommodates a high mass loading of the micro-scale MoS2 nano-flowers. MoS2 nano-flowers with open architecture deliver large specific area. The rGO interlayers act as a conductive framework, making all flower-like MoS2 nano-stuffing electrochemically active. The ultra-thin 2D nano-sheets provide excellent cycle stability due to their neglectable volume changes during cycling. The 3D flower-like MoS2-PrGO sandwich composites deliver high energy density, excellent conductivity and stable cyclic performance during charge-discharge process. With a nearly 100% coulombic efficiency, their reversible capacity is retained at 1,036 mA h g-1 even after 500 cycles at current densities of 100 mA g-1. This novel design strategy provides a broad prospect for the development of advanced anode materials for superior lithium storage.

| S-EPMC7058583 | biostudies-literature

Enhanced Dielectric Performance of P(VDF-HFP) Composites with Satellite-Core-Structured Fe2O3@BaTiO3 Nanofillers.

Project description:Polymer dielectric materials are extensively used in electronic devices. To enhance the dielectric constant, ceramic fillers with high dielectric constant have been widely introduced into polymer matrices. However, to obtain high permittivity, a large added amount (>50 vol%) is usually needed. With the aim of improving dielectric properties with low filler content, satellite-core-structured Fe2O3@BaTiO3 (Fe2O3@BT) nanoparticles were fabricated as fillers for a poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) matrix. The interfacial polarization effect is increased by Fe2O3 nanoparticles, and thus, composite permittivity is enhanced. Besides, the satellite-core structure prevents Fe2O3 particles from directly contacting each other, so that the dielectric loss remains relatively low. Typically, with 20 vol% Fe2O3@BT nanoparticle fillers, the permittivity of the composite is 31.7 (1 kHz), nearly 1.8 and 3.0 times that of 20 vol% BT composites and pure polymers, respectively. Nanocomposites also achieve high breakdown strength (>150 KV/mm) and low loss tangent (~0.05). Moreover, the composites exhibited excellent flexibility and maintained good dielectric properties after bending. These results demonstrate that composite films possess broad application prospects in flexible electronics.

| S-EPMC6835555 | biostudies-literature

Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage.

Project description:Supercapacitors now play an important role in the progress of hybrid and electric vehicles, consumer electronics, and military and space applications. There is a growing demand in developing hybrid supercapacitor systems to overcome the energy density limitations of the current generation of carbon-based supercapacitors. Here, we demonstrate 3D high-performance hybrid supercapacitors and microsupercapacitors based on graphene and MnO2 by rationally designing the electrode microstructure and combining active materials with electrolytes that operate at high voltages. This results in hybrid electrodes with ultrahigh volumetric capacitance of over 1,100 F/cm(3). This corresponds to a specific capacitance of the constituent MnO2 of 1,145 F/g, which is close to the theoretical value of 1,380 F/g. The energy density of the full device varies between 22 and 42 Wh/l depending on the device configuration, which is superior to those of commercially available double-layer supercapacitors, pseudocapacitors, lithium-ion capacitors, and hybrid supercapacitors tested under the same conditions and is comparable to that of lead acid batteries. These hybrid supercapacitors use aqueous electrolytes and are assembled in air without the need for expensive "dry rooms" required for building today's supercapacitors. Furthermore, we demonstrate a simple technique for the fabrication of supercapacitor arrays for high-voltage applications. These arrays can be integrated with solar cells for efficient energy harvesting and storage systems.

| S-EPMC4394298 | biostudies-literature

Three-dimensional metal-intercalated covalent organic frameworks for near-ambient energy storage.

Project description:A new form of nanoporous material, metal intercalated covalent organic framework (MCOF) is proposed and its energy storage property revealed. Employing density functional and thermodynamical analysis, we find that stable, chemically active, porous materials could form by stacking covalent organic framework (COF) layers with metals as a gluing agent. Metal acts as active sites, while its aggregation is suppressed by a binding energy significantly larger than the corresponding cohesive energy of bulk metals. Two important parameters, metal binding and metal-metal separation, are tuned by selecting suitable building blocks and linkers when constructing COF layers. Systematic searches among a variety of elements and organic molecules identify Ca-intercalated COF with diphenylethyne units as optimal material for H2 storage, reaching a striking gravimetric density ~ 5 wt% at near-ambient conditions (300 K, 20 bar), in comparison to < 0.1 wt% for bare COF-1 under the same condition.

| S-EPMC3662009 | biostudies-other

Construction of self-supported three-dimensional TiO2 sheeted networks with enhanced photocatalytic activity.

Project description:The degradation of toxic gases and liquids using a catalyst and solar energy is an ideal method, compared with landfill and combustion methods. The search for active semiconductor photocatalysts that efficiently decompose contaminations under light irradiation remains one of the most challenging tasks for solar-energy utilization. In this work, free-supporting three-dimensional (3D) nanosheeted hierarchical porous tungsten, titanium, and tin oxide networks were obtained by a facile Lewis acid catalytic binary template route. These networks possess large macroscopic scale (millimeter-sized) and hierarchical macro/mesoporous nanostructure with high surface area and large pore volume. Photocatalytic degradation of Azo dyes demonstrated that the nanosheets-constructed hierarchical porous networks have high photocatalytic activity and stability. The present synthetic route can serve as the new design concept for functional 3D layered porous nanostructures.

| S-EPMC3868961 | biostudies-literature

Three-dimensional Graphene with MoS <sub>2</sub> Nanohybrid as Potential Energy Storage/Transfer Device.

Project description:Portable and matured energy storage devices are in high demand for future flexible electronics. Flowery shaped MoS2 nanostructures with porous and flake like morphology was used to study the supercapacitive nature with specific capacitance (C sp ) of 169.37F/g, the energy density of 28.43?Wh/Kg and power density of 10.18?W/Kg. This nanoflower like architecture was decorated on 3D-graphene on Graphite electrode to design the solid-state-supercapacitor prototype device of dimensions of 23.6?×?22.4?×?0.6?mm3 having considerable high Csp of 58.0F/g and energy density of 24.59?Wh/Kg, and power density of 8.8?W/Kg. Four fabricated supercapacitors were connected in series for real state practical demonstration using the light emitting diode that remains enlightened for 40?s by charging it only for 25?s. This study demonstrates the 3D-graphene/MoS2 nanohybrid has a quite high overall potential window nearly about 2.7?V (-1.5 to +1.2?V) in KOH-PVA medium which can be used for the development of solid-state supercapacitors thereby completely eliminating the need for any expensive ionic liquid mediums thus building an exciting potential for high-performance energy storage/transfer devices.

| S-EPMC5573343 | biostudies-literature

Enhanced Microwave Absorption and Electromagnetic Properties of Si-Modified rGO@Fe3O4/PVDF-co-HFP Composites.

Project description:Graphene has been regarded as one of the most promising two-dimensional nanomaterials. Even so, graphene was still faced with several key issues such as impedance mismatching and narrow bandwidth, which have hindered the practical applications of graphene-based nanocomposites in the field of microwave absorption materials. Herein, a series of Si-modified rGO@Fe3O4 composites were investigated and fabricated by a simple method. On one hand, the degree of defects in graphene carbon could be tuned by different silane coupling reagents, which were beneficial to enhancing the dielectric loss. On the other hand, the spherical Fe3O4 nanoparticles provided the magnetic loss resonance, which contributed to controlling the impedance matching. Subsequently, the electromagnetic absorption (EMA) properties of Si-modified rGO@Fe3O4 composites with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP) were investigated in this work. As a result, the Si(2)-rGO@Fe3O4/PVDF-co-HFP composite exhibited the excellent EMA performance in the range of 2-18 GHz. The maximum reflection loss (RLmax) reached -32.1 dB at 3.68 GHz at the thickness of 7 mm and the effective absorption frequency bandwidth for reflection loss (RL) below -10 dB was 4.8 GHz at the thickness of 2 mm. Furthermore, the enhanced absorption mechanism revealed that the high-efficiency absorption performance of Si(2)-rGO@Fe3O4/PVDF-co-HFP composite was attributed to the interference absorption (quarter-wave matching model) and the synergistic effects between Si(2)-rGO@Fe3O4 and PVDF-co-HFP. This work provides a potential strategy for the fabrication of the high-performance EMA materials.

| S-EPMC7079640 | biostudies-literature

Dye-sensitized solar cell with energy storage function through PVDF/ZnO nanocomposite counter electrode.

Project description:Dye-sensitized solar cells with an energy storage function are demonstrated by modifying its counter electrode with a poly (vinylidene fluoride)/ZnO nanowire array composite. This simplex device could still function as an ordinary solar cell with a steady photocurrent output even after being fully charged. An energy storage density of 2.14 C g(-1) is achieved, while simultaneously a 3.70% photo-to-electric conversion efficiency is maintained.

| S-EPMC3796954 | biostudies-literature

Enhanced energy density of PVDF-based nanocomposites via a core-shell strategy.

Project description:In recent years, high energy density polymer capacitors have attracted a lot of scientific interest due to their potential applications in advanced power systems and electronic devices. Here, core-shell structured TiO2@SrTiO3@polydamine nanowires (TiO2@SrTiO3@PDA NWs) were synthesized via a combination of surface conversion reaction and in-situ polymerization method, and then incorporated into the poly(vinylidene fluoride) (PVDF) matrix. Our results showed that a small amount of TiO2@SrTiO3@PDA NWs can simultaneously enhance the breakdown strength and electric displacement of nanocomposite (NC) films, resulting in improved energy storage capability. The 5 wt% TiO2@SrTiO3@PDA NWs/PVDF NC demonstrates 1.72 times higher maximum discharge energy density compared to pristine PVDF (10.34 J/cm3 at 198 MV/m vs. 6.01 J/cm3 at 170 MV/m). In addition, the NC with 5 wt% TiO2@SrTiO3@PDA NWs also demonstrates an excellent charge-discharge efficiency (69% at 198 MV/m). Enhanced energy storage performance is due to hierarchical interfacial polarization among their multiple interfaces, the large aspect ratio as well as surface modification of the TiO2@SrTiO3 NWs. The results of this study provide guidelines and a foundation for the preparation of the polymer NCs with an outstanding discharge energy density.

| S-EPMC7555536 | biostudies-literature