Unknown

Dataset Information

0

Photocatalytic acyl azolium-promoted alkoxycarbonylation of trifluoroborates.


ABSTRACT: Despite recent advancements in the selective generation and coupling of organic radical species, the alkoxycarbonyl radical remains underexplored relative to other carbon-containing radical species. Drawing inspiration from new strategies for generating acyl radical equivalents utilizing dual N-heterocyclic carbene catalysis and photocatalysis, we have prepared dimethylimidazolium esters that can function as an alkoxycarbonyl radical surrogate under photocatalytic conditions. We demonstrate the synthetic utility of these azolium-based partners through the preparation of esters arising from the coupling of this radical surrogate with an oxidatively generated alkyl radical.

SUBMITTER: Zhu JL 

PROVIDER: S-EPMC8274565 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6648278 | biostudies-literature
| S-EPMC8672810 | biostudies-literature
| S-EPMC8712972 | biostudies-literature
| S-EPMC8694347 | biostudies-literature
| S-EPMC3193542 | biostudies-literature
| S-EPMC4921810 | biostudies-other
| S-EPMC5566346 | biostudies-literature
| S-EPMC8145243 | biostudies-literature
| S-EPMC5288498 | biostudies-literature
| S-EPMC7988452 | biostudies-literature