An Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization.
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ABSTRACT: A robust synthesis of gem-dialkyl acyclic diene monomers has been developed. This route is scalable, flexible, and biorenewable, allowing for the production of a wide range of diene monomers of different lengths and different gem-dialkyl substitution starting from unsaturated esters derived from seed oils. The metathesis polymerization of these monomers and the hydrogenation of the resulting polyolefins leads to telechelic gem-dialkyl polyethylenes, which can be used as elastomers in the synthesis of polyurethanes and other block polymers.
SUBMITTER: Wolf WJ
PROVIDER: S-EPMC8297823 | biostudies-literature |
REPOSITORIES: biostudies-literature
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