Dataset Information

Investigation of 9000 hours multi-stress aging effects on High-Temperature Vulcanized Silicone Rubber with silica (nano/micro) filler hybrid composite insulator.

ABSTRACT: Degradation in the polymeric insulators is caused due to the environmental stresses. The main aim of this paper is to explore the improved aging characteristics of hybrid samples by adding nano/micro silica in High Temperature Vulcanized Silicone Rubber (HTV-SiR) under long term accelerated aging conditions for 9000 hours. As HTV-SiR is unable to sustain environmental stresses for a long time, thus a long term accelerated aging behavior is an important phenomenon to be considered for field application. The aging characteristics of nano/micro filled HTV-SiR are analyzed by using techniques such as Scanning Electron Microscopy (SEM), Leakage Current (LC), Fourier Transform Infrared Microscopy (FTIR), Hydrophobicity Classification (HC), and breakdown strength for the aging time of 9000 hours. FTIR and leakage currents are measured after every cycle. All the co-filled samples revealed escalated aging characteristics as compared to the neat sample except the SN8 sample (8% nano-silica+20% micro-silica) after 9000 hours of aging. The highest loading of 6% and 8% nano-silica with 20% micro-silica do not contribute to the improved performance when compared with the neat and hybrid samples. However, from the critical experimental analysis, it is deduced that SN2 sample (2% nano-silica+20% micro-silica) is highly resistant to the long term accelerated aging conditions. SN2 has no cracks, lower loss percentages in the important FTIR absorption peaks, higher breakdown strength and superior HC after aging as compared to the unfilled and hybrid samples.

SUBMITTER: Rashid A

PROVIDER: S-EPMC8318273 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Similar Datasets

Project description:ObjectivesMaxillofacial silicone is used to restore abnormalities due to congenital or acquired causes. However, the quality of silicone is far from ideal. This study was aimed at assessing the influence of the addition of cellulose nanofibers (CNFs; several nanometers in diameter and 2-5 μm long) on the physical and mechanical characteristics of maxillofacial silicone elastomers.MethodsTwo CNF weight percentages (0.5% and 1%) were tested, and 180 specimens were divided into one control and two experimental groups. Each group was subdivided into six subgroups. In each subgroup, ten specimens subjected to each of the following tests: tearing strength, Shore-A hardness, tensile strength, elongation percentage, surface roughness, and color stability. The samples were additionally analyzed with Fourier transform infrared spectroscopy (FTIR) and field emission scanning electronic microscopy (FESEM).ResultsThe 0.5% CNF group, compared with the control group, exhibited highly significantly greater tearing strength, elongation percentage, hardness Shore-A, and surface roughness, and substantially greater tensile strength. However, color stability did not significantly differ between groups.The 1% CNF group showed significantly greater Shore-A hardness, tear strength, color stability, and surface roughness, and insignificantly lower tensile strength and percentage elongating values, than the control group. FESEM imaging revealed good CNF dispersion. The FTIR spectra indicated that CNFs interacted with silicone through surface functional hydroxyl groups.ConclusionAddition of 0.5 wt. % CNF to silicone elastomers increased the material's mechanical tensile strength, tear strength, elongation percentage, and hardness as long as it stayed within the acceptable range for clinical use. Surface roughness increased in direct proportion to the amount of nanofibers added. Moreover, addition of 0.5 wt. % CNF to silicone polymers had insignificant effects on color stability.

Project description:Although natural rubber was regarded as biodegradable, the degradation is a time-consuming process that could take weeks or months for any degradation or substantial weight loss to be observable, resulting in the need for novel processes/methods to accelerate the rubber degradation. As a result, this work investigated the potential utilization of chitosan (CS) as a biodegradation enhancer for radiation-vulcanized natural rubber latex (R-VNRL) and hybrid radiation and peroxide-vulcanized natural rubber latex (RP-VNRL) composites, with varying CS contents (0, 2, 4, or 6 phr). The R-VNRL samples were prepared using 15 kGy gamma irradiation, while the RP-VNRL samples were prepared using a combination of 0.1 phr tert-butyl hydroperoxide (t-BHPO) and 10 kGy gamma irradiation. The properties investigated were biodegradability in the soil and the morphological, chemical, mechanical, and physical properties, both before and after undergoing thermal aging. The results indicated that the biodegradability of both the R-VNRL and RP-VNRL composites was enhanced with the addition of CS, as evidenced by increases in the percentage weight loss (% weight loss) after being buried in soil for 8 weeks from 6.5 ± 0.1% and 6.4 ± 0.1% in a pristine R-VNRL and RP-VNRL samples, respectively, to 10.5 ± 0.1% and 10.2 ± 0.1% in 6-pph CS/R-VNRL and 6-pph CS/RP-VNRL composites, respectively, indicating the biodegradation enhancement of approximately 60%. In addition, the results revealed that the addition of CS could increase the value of tensile modulus by 119%, while decrease the values of tensile strength and elongation at break by 50% and 43%, respectively, in the specimens containing 6-phr CS. In terms of the color appearances, the samples were lighter and yellower after the addition of CS, as evidenced by the noticeably increased L* and b* values, based on the CIE L*a*b* color space system. Furthermore, the investigation into the effects of thermal aging showed that the overall tensile properties for both curing systems were reduced, while varying degrees of color change were observed, with the pristine R-VNRL and RP-VNRL samples having more pronounced degradation/changes for both properties. In conclusion, the overall results suggested that CS had great potential to be applied as a bio-filler in R-VNRL and RP-VNRL composites to effectively promote the biodegradability, environmental friendliness, and resistance to thermal degradation of the composites.

Dataset Information

Investigation of 9000 hours multi-stress aging effects on High-Temperature Vulcanized Silicone Rubber with silica (nano/micro) filler hybrid composite insulator.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets