Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Study of the Hydrogen Storage Properties and Catalytic Mechanism of a MgH₂-Na₃AlH₆ System Incorporating FeCl₃.

ABSTRACT: In this work, the catalytic effects of FeCl₃ toward the hydrogen storage properties of the MgH₂-Na₃AlH₆ composite were investigated for the first time. The temperature-programed desorption results indicated that the onset temperature of the hydrogen release of a 10 wt % FeCl₃-doped MgH₂-Na₃AlH₆ composite was ∼30 °C lower than that of the undoped MgH₂-Na₃AlH₆ composite. The addition of FeCl₃ into the MgH₂-Na₃AlH₆ composite resulted in improved absorption and desorption kinetics performance. The absorption/desorption kinetics measurements at 320 °C (under 33 and 1 atm hydrogen pressure, respectively) indicated that within 10 min, the doped sample absorbed ∼4.0 wt % and desorbed ∼1.5 wt % hydrogen. By comparison, the undoped sample absorbed only ∼2.1 wt % and desorbed only ∼0.6 wt % hydrogen under the same conditions and time. Comparably, the apparent activation energy value of the doped composite is 128 kJ/mol, which is 12 kJ/mol lower than that of the undoped composite (140 kJ/mol). The formation of the new species of MgCl₂ and Fe in the doped composite was detected from X-ray diffraction analysis after heating and absorption processes. These two components were believed to play a vital role in reducing the decomposition temperature and kinetics enhancement of the MgH₂-Na₃AlH₆ composite.

SUBMITTER: Halim Yap MFAA

PROVIDER: S-EPMC8320109 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Synthetic nanocomposite MgH2/5 wt. % TiMn2 powders for solid-hydrogen storage tank integrated with PEM fuel cell.

Project description:Storing hydrogen gas into cylinders under high pressure of 350?bar is not safe and still needs many intensive studies dedic ated for tank's manufacturing. Liquid hydrogen faces also severe practical difficulties due to its very low density, leading to larger fuel tanks three times larger than traditional gasoline tank. Moreover, converting hydrogen gas into liquid phase is not an economic process since it consumes high energy needed to cool down the gas temperature to -252.8?°C. One practical solution is storing hydrogen gas in metal lattice such as Mg powder and its nanocomposites in the form of MgH2. There are two major issues should be solved first. One related to MgH2 in which its inherent poor hydrogenation/dehydrogenation kinetics and high thermal stability must be improved. Secondly, related to providing a safe tank. Here we have succeeded to prepare a new binary system of MgH2/5 wt. % TiMn2 nanocomposite powder that show excellent hydrogenation/dehydrogenation behavior at relatively low temperature (250?°C) with long cycle-life-time (1400?h). Moreover, a simple hydrogen storage tank filled with our synthetic nanocomposite powders was designed and tested in electrical charging a battery of a cell phone device at 180?°C through a commercial fuel cell.

| S-EPMC5643390 | biostudies-literature

Ab Initio Screening of Doped Mg(AlH4)2 Systems for Conversion-Type Lithium Storage.

Project description:In this work, we have explored the potential applications of pure and various doped Mg(AlH4)2 as Li-ion battery conversion electrode materials using density functional theory (DFT) calculations. Through the comparisons of the electrochemical specific capacity, the volume change, the average voltage, and the electronic bandgap, the Li-doped material is found to have a smaller bandgap and lower average voltage than the pure system. The theoretical specific capacity of the Li-doped material is 2547.64 mAhg-1 with a volume change of 3.76% involving the electrode conversion reaction. The underlying reason for property improvement has been analyzed by calculating the electronic structures. The strong hybridization between Lis-state with H s-state influences the performance of the doped material. This theoretical research is proposed to help the design and modification of better light-metal hydride materials for Li-ion battery conversion electrode applications.

| S-EPMC6719994 | biostudies-literature

Regio/Site-Selective Benzoylation of Carbohydrates by Catalytic Amounts of FeCl3.

Project description:This work uncovered the regio/site-selective benzoylation of 1,2- and 1,3-diols and glycosides containing a cis-vicinal diol using a catalytic amount of FeCl3 with the assistance of acetylacetone. FeCl3 may initially form [Fe(acac)3] (acac = acetylacetonate) with excess acetylacetone in the presence of diisopropylethylamine (DIPEA) in acetonitrile at room temperature. Then, benzoylation was catalyzed by Fe(acac)3 with added benzoyl chloride in the presence of DIPEA under mild conditions as reported. This reaction produced selectivities and isolated yields similar to or slightly lower than the reaction using Fe(acac)3 as a catalyst in most cases. The result provides not only the green and convenient selective benzoylation method associated with the most inexpensive catalysts but also the possibility that the effects of various metal salts and ligands on the regioselective protection can be extensively investigated in future study to obtain the optimized catalytic system.

| S-EPMC6643987 | biostudies-literature

Comments on "Evidence of the hydrogen release mechanism in bulk MgH2".

Project description:The effect of an electron beam induced dehydrogenation of MgH2 in the transmission electron microscope (TEM) is largely underestimated by Nogita et al., and led the authors to a misinterpretation of their TEM observations. Firstly, the selected area diffraction (SAD) pattern is falsely interpreted. A re-evaluation of the SAD pattern reveals that no MgH2 is present in the sample, but that it rather consists of Mg and MgO only. Secondly, the transformation of the sample upon in-situ heating in the TEM cannot be ascribed to dehydrogenation, but is rather to be explained by the (nanoscale) Kirkendall effect, which leads to the formation of hollow MgO shells without any metallic Mg in their cores. Hence, the conclusions drawn from the TEM investigation are invalid, as the authors apparently have never studied MgH2.

| S-EPMC5384078 | biostudies-literature

Crystal Structural Investigations for Understanding the Hydrogen Storage Properties of YMgNi4-Based Alloys.

Project description:The hydrogen storage properties and crystal structures of YMgNi4-based alloys, which were synthesized from (2 - x)YNi2 and xMgNi2 (0.6 ? x ? 1.2), were investigated by pressure-composition-temperature measurements and powder neutron diffraction at a deuterium gas pressure to understand the hydrogen absorption and desorption reactions viewed from atomic arrangements around H atoms. Reducing the amounts of MgNi2, which was utilized as a Mg source in YMgNi4-based alloys, has been observed to lower the hydrogen absorption and desorption pressures and increase the hydrogen storage capacities. However, the reversible hydrogen capacity attained a maximum value of 1.2 mass % at x = 0.8 because of the formation of a thermodynamically stable hydride in which hydrogen was not released at x = 0.6. In the case of x = 0.6, the presence of excessive Y atoms around the H atoms in the hydrogen-absorbed phase would lead to the formation of a hydride with stronger interaction between Y and H because of the affinity between them. Moreover, the presence of small amounts of D atoms with short interatomic D-D distances (1.6 and 1.9 Å) in the deuterium-absorbed phase (Y0.81Mg1.19Ni4.00D3.35 and Y1.06Mg0.94Ni4.00D3.86) at <5 MPa and 323 K was proposed by the crystal structural investigations. The D atoms with short D-D interatomic distances were located in the same local atomic arrangements of D atoms in a deuterium-absorbed phase, which were formed at a higher-pressure range, and had higher hydrogen storage capacities than the deuterium-absorbed phases in this study.

| S-EPMC7726944 | biostudies-literature

Effects of FeCl3 Catalytic Hydrothermal Carbonization on Chemical Activation of Corn Wet Distillers' Fiber.

Project description:Corn wet distillers' fiber (corn fiber) is a byproduct of the corn-ethanol production process, with high potential as a precursor for activated carbon due to its moderate nitrogen content and availability. However, there has been limited investigation into activated carbons from the corn fiber. In this work, we produce activated carbons from the corn fiber using three procedures, including direct KOH activation, hydrothermal carbonization (HTC) followed by KOH activation, and FeCl3-catalyzed HTC followed by KOH activation. Catalytic HTC with FeCl3 was found to slightly increase the degree of carbonization relative to uncatalyzed HTC while also removing the nitrogen content at increasing concentrations and slightly increasing the porosity. The resulting activated carbon samples are then characterized by thermal gravimetric analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, and nitrogen analysis. The two-step process resulted in activated carbon with substantially higher surface areas than the one-step process (1220 vs 789 m2/g), as well as much higher thermal stability and nitrogen content (up to 1.20%). The results show that the corn fiber has potential for activated carbon production, with the two-step HTC followed by the activation process producing more favorable material properties than direct activation.

| S-EPMC8209796 | biostudies-literature

Improved Na+/K+ Storage Properties of ReSe2-Carbon Nanofibers Based on Graphene Modifications.

Project description:Rhenium diselenide (ReSe2) has caused considerable concerns in the field of energy storage because the compound and its composites still suffer from low specific capacity and inferior cyclic stability. In this study, ReSe2 nanoparticles encapsulated in carbon nanofibers were synthesized successfully with simple electrospinning and heat treatment. It was found that graphene modifications could affect considerably the microstructure and electrochemical properties of ReSe2-carbon nanofibers. Accordingly, the modified compound maintained a capacity of 227 mAh g-1 after 500 cycles at 200 mA g-1 for Na+ storage, 230 mAh g-1 after 200 cycles at 200 mA g-1, 212 mAh g-1 after 150 cycles at 500 mA g-1 for K+ storage, which corresponded to the capacity retention ratios of 89%, 97%, and 86%, respectively. Even in Na+ full cells, its capacity was maintained to 82% after 200 cycles at 1C (117 mA g-1). The superior stability of ReSe2-carbon nanofibers benefitted from the extremely weak van der Waals interactions and large interlayer spacing of ReSe2, in association with the role of graphene-modified carbon nanofibers, in terms of the shortening of electron/ion transport paths and the improvement of structural support. This study may provide a new route for a broadened range of applications of other rhenium-based compounds.

| S-EPMC7770771 | biostudies-literature

Transmission Properties of FeCl3-Intercalated Graphene and WS2 Thin Films for Terahertz Time-Domain Spectroscopy Applications.

Project description:Time-resolved terahertz spectroscopy has become a common method both for fundamental and applied studies focused on improving the quality of human life. However, the issue of finding materials applicable in these systems is still relevant. One of the appropriate solution is 2D materials. Here, we demonstrate the transmission properties of unique graphene-based structures with iron trichloride FeCl3 dopant on glass, sapphire and Kapton polyimide film substrates that previously were not investigated in the framework of the above-described problems in near infrared and THz ranges. We also show properties of a thin tungsten disulfide WS2 film fabricated from liquid crystal solutions transferred to a polyimide and polyethylene terephthalate substrates. The introduction of impurities, the selection of structural dimensions and the use of an appropriate substrate for modified 2D layered materials allow to control the transmission of samples for both the terahertz and infrared ranges, which can be used for creation of effective modulators and components for THz spectroscopy systems.

| S-EPMC6616562 | biostudies-literature

FeCl2-Mediated Rearrangement of Allylic Alcohols.

Project description:A mild, one-pot procedure to produce 3-substituted allylic alcohols from α,β-unsaturated ketones is described. The addition of an organolithium nucleophile produces a tertiary allylic alcohol as an intermediate, which undergoes a 1,3-OH-migration assisted by FeCl2. The proposed mechanism indicates that a syn-facial migration occurs for the major product. Yields as high as 98% for the one-pot reaction are reported.

| S-EPMC6648291 | biostudies-literature

Realizing a High-Performance Na-Storage Cathode by Tailoring Ultrasmall Na2FePO4F Nanoparticles with Facilitated Reaction Kinetics.

Project description:In this paper, the synthesis of ultrasmall Na2FePO4F nanoparticles (?3.8 nm) delicately embedded in porous N-doped carbon nanofibers (denoted as Na2FePO4F@C) by electrospinning is reported. The as-prepared Na2FePO4F@C fiber film tightly adherent on aluminum foil features great flexibility and is directly used as binder-free cathode for sodium-ion batteries, exhibiting admirable electrochemical performance with high reversible capacity (117.8 mAh g-1 at 0.1 C), outstanding rate capability (46.4 mAh g-1 at 20 C), and unprecedentedly high cyclic stability (85% capacity retention after 2000 cycles). The reaction kinetics and mechanism are explored by a combination study of cyclic voltammetry, ex situ structure/valence analyses, and first-principles computations, revealing the highly reversible phase transformation of Na2FeIIPO4F ? NaFeIIIPO4F, the facilitated Na+ diffusion dynamics with low energy barriers, and the desirable pseudocapacitive behavior for fast charge storage. Pouch-type Na-ion full batteries are also assembled employing the Na2FePO4F@C nanofibers cathode and the carbon nanofibers anode, demonstrating a promising energy density of 135.8 Wh kg-1 and a high capacity retention of 84.5% over 200 cycles. The distinctive network architecture of ultrafine active materials encapsulated into interlinked carbon nanofibers offers an ideal platform for enhancing the electrochemical reactivity, electronic/ionic transmittability, and structural stability of Na-storage electrodes.

| S-EPMC6662290 | biostudies-literature